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Explain why does a S(N^2) reaction invol...

Explain why does a `S_(N^2)` reaction involve an inversion in configuration.

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Assertion : SN_(2) reaction of an optically active aryl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation. Reason : S_(N) reactions always proceed with inversion of configuration.

In the following S_(N)2 reaction

(i) Which alkyI hailde from the following pair is chiral and undergoes faster S_(N)2 reaction ? (ii) Out of S_(N)1 and S_(N)2 which reaction occurs with (a) Inversion of configuration (b) Recemisation

Write the reaction involved in N_2 - fixation

Consider the statements for given reaction 1. In the first step, there is breaking of C - O bond 2. The second step is S_(N)2 reaction 3. There is retention of configuration in the first step 4. There is inversion of configuration in the second step

Consider the ollowing statement about SN^(1) reaction (i) it is a bimolecular reaction (ii) it proceeds with retention as well as inversion of the configuration. (iii) It involves the fomrationn of an intermediate cabocation (iv) The reaction is carried in the presence of polar aprotic solvents

Explain why lonic reactions are very fast.

ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -SHORT ANSWER TYPE QUESTIONS
  1. What do you understand by hyperconjugation effect ? Illustrate with an...

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  2. Explain the Hyperconjugation effect is also termed as 'no bond reso...

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  3. Why is the hyperconjugation effect exerted by a methyl group greater t...

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  4. Define heterolytic fission of a covalent bond.

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  5. Why is a 3^@ radical more stable as compared to 1^@ and 2^@ free r...

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  6. What are carbocations ? Give two examples.

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  7. Discuss the orbital structure of a carbocation.

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  8. What is relative order of reactivity of various types of carbocations ...

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  9. Define carbanion and discuss its orbital structure.

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  10. Why is 1^@ carbanion more stable than a 2 carbanion ?

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  11. What are carbenes ?

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  12. What are electrophilic reagents ? Give at least three examples.

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  13. Why do free radicals and carbenes act as electrophiles ?

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  14. What do you understand by nucleophilic reagents and what type of speci...

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  15. Why does ether act as a nucleophile ?

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  16. What are nucleophilic substitution reactions ? Give an example.

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  17. What are the reactive species involved in S(N^1) reactions ?

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  18. Explain why does a S(N^2) reaction involve an inversion in configurati...

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  19. Give three examples of electrophilic substitution reactions.

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  20. Discuss the mechanism of anti-Markownikoff addition of HBr to an unsym...

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