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In tautomerism, the two tautomeric forms...

In tautomerism, the two tautomeric forms continuously change into each other through the oscillation of

A

a proton

B

`pi`-electrons

C

a proton and `pi`-electrons

D

none of the above.

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The correct Answer is:
To solve the question regarding tautomerism and the oscillation of species involved, we can break down the explanation into clear steps: ### Step-by-Step Solution: 1. **Understanding Tautomerism**: Tautomerism is a special type of isomerism where two isomers (tautomers) exist in dynamic equilibrium and differ in the position of a proton and the arrangement of electrons. 2. **Identifying Tautomeric Forms**: A common example of tautomerism is the equilibrium between ketones and enols. For instance, propanone (CH3C(=O)CH3) can tautomerize to its enol form (CH3C(OH)=CH2). 3. **Proton Transfer**: In the tautomerization process, a proton (H+) is transferred from the alpha carbon (the carbon adjacent to the carbonyl group) to the oxygen atom in the carbonyl group. This transfer is crucial in converting the ketone to the enol form. 4. **Electron Movement**: Along with the proton transfer, there is also a movement of electrons. Specifically, the pi electrons from the carbonyl double bond shift to form a new bond with the oxygen atom, while the electrons from the C-H bond are involved in the formation of the new double bond in the enol. 5. **Conclusion**: Therefore, the two tautomeric forms continuously change into each other through the oscillation of both a proton and pi electrons. ### Final Answer: The correct answer is **C: a proton and pi electrons**.

To solve the question regarding tautomerism and the oscillation of species involved, we can break down the explanation into clear steps: ### Step-by-Step Solution: 1. **Understanding Tautomerism**: Tautomerism is a special type of isomerism where two isomers (tautomers) exist in dynamic equilibrium and differ in the position of a proton and the arrangement of electrons. 2. **Identifying Tautomeric Forms**: ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. Write the structures of three ethers with molecular formula C(4)H(10)...

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  2. Propanal is the functional isomer of

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  3. In tautomerism, the two tautomeric forms continuously change into each...

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  4. The enolic form of CH3 -overset(O ) overset(।। )C- CH2 COOC2 H5 is

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  5. How many chain isomers are possible with the formula C7 H(16) ?

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  6. The isomerism shown by butan-1-amine and 2-methylpropan l-amine is

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  7. The number of conformations exhibited by ethane is

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  8. Which of the following statements is correct?

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  9. At room temperature, the staggered and eclipsed conformers of ethane c...

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  10. Which of the following letters possesses chirality ? A X H J

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  11. A compound of the type C(abd) - C(abd)

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  12. The compound represented by the following structure {:(" "COOH)...

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  13. Which of the following compounds does possess one or more asymmetric c...

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  14. The d- and l- forms of an optically active compound are called

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  15. Lactic acid (2-hydroxypropanoic acid) is an optically active compound....

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  16. When pyruvic acid (CH3 -overset(O )overset(|| ) C-COOH) is reduced und...

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  17. Which of the following types of compounds is unable to exhibit geometr...

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  18. Write the systematic IUPAC names of the following compounds : C6 H5...

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  19. Which of the following compounds cannot exist in cis and trans forms?

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  20. Which of the following statements is not correct?

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