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The enolic form of CH3 -overset(O ) over...

The enolic form of `CH_3 -overset(O ) overset(।। )C- CH_2 COOC_2 H_5` is

A

`CH_2 = overset(OH) overset(|) C - CH_2 COOC_2 H_5`

B

`CH_3 - overset(OH)overset(|) C = CHCOOC_2 H_5`

C

`CH_3 - overset(O ) overset(||) C- CH = overset(OH) overset(|)C-COOC_2 H_5 `

D

none of the above.

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The correct Answer is:
To find the enolic form of the compound \( CH_3 - C(=O) - CH_2 - COO - C_2H_5 \), we will follow these steps: ### Step 1: Identify the Keto Form The given compound is in its keto form, which is characterized by the presence of a carbonyl group (C=O). The structure can be represented as: \[ CH_3 - C(=O) - CH_2 - COO - C_2H_5 \] ### Step 2: Recognize the Active Methylene Group In the compound, the methylene group \( CH_2 \) is situated between two carbonyl groups (C=O). This methylene group is referred to as an "active methylene group" because it has acidic hydrogen atoms that can participate in tautomerism. ### Step 3: Tautomerism Process Tautomerism involves the transfer of a hydrogen atom and the rearrangement of double bonds. In this case, the hydrogen atom from the active methylene group will shift to the oxygen atom of the carbonyl group. The double bond will then shift to form a new double bond between the carbon and the adjacent carbon atom. ### Step 4: Write the Enolic Form After the tautomeric shift, the enolic form of the compound can be represented as: \[ CH_3 - C(OH) = CH - C(=O) - O - C_2H_5 \] This structure shows that we now have a hydroxyl group (OH) and a double bond (C=C), which is characteristic of enols. ### Final Enolic Form Thus, the enolic form of the compound \( CH_3 - C(=O) - CH_2 - COO - C_2H_5 \) is: \[ CH_3 - C(OH) = CH - C(=O) - O - C_2H_5 \] ---

To find the enolic form of the compound \( CH_3 - C(=O) - CH_2 - COO - C_2H_5 \), we will follow these steps: ### Step 1: Identify the Keto Form The given compound is in its keto form, which is characterized by the presence of a carbonyl group (C=O). The structure can be represented as: \[ CH_3 - C(=O) - CH_2 - COO - C_2H_5 \] ### Step 2: Recognize the Active Methylene Group In the compound, the methylene group \( CH_2 \) is situated between two carbonyl groups (C=O). This methylene group is referred to as an "active methylene group" because it has acidic hydrogen atoms that can participate in tautomerism. ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. Propanal is the functional isomer of

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  2. In tautomerism, the two tautomeric forms continuously change into each...

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  3. The enolic form of CH3 -overset(O ) overset(।। )C- CH2 COOC2 H5 is

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  4. How many chain isomers are possible with the formula C7 H(16) ?

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  5. The isomerism shown by butan-1-amine and 2-methylpropan l-amine is

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  6. The number of conformations exhibited by ethane is

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  7. Which of the following statements is correct?

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  8. At room temperature, the staggered and eclipsed conformers of ethane c...

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  9. Which of the following letters possesses chirality ? A X H J

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  10. A compound of the type C(abd) - C(abd)

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  11. The compound represented by the following structure {:(" "COOH)...

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  12. Which of the following compounds does possess one or more asymmetric c...

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  13. The d- and l- forms of an optically active compound are called

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  14. Lactic acid (2-hydroxypropanoic acid) is an optically active compound....

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  15. When pyruvic acid (CH3 -overset(O )overset(|| ) C-COOH) is reduced und...

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  16. Which of the following types of compounds is unable to exhibit geometr...

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  17. Write the systematic IUPAC names of the following compounds : C6 H5...

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  18. Which of the following compounds cannot exist in cis and trans forms?

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  19. Which of the following statements is not correct?

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  20. Consider the following conformations. Which of the following statement...

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