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How many optically active stereoisomers ...

How many optically active stereoisomers are possible for butane-2, 3-diol
1
2
3
4

A

1

B

2

C

3

D

4

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The correct Answer is:
To determine how many optically active stereoisomers are possible for butane-2,3-diol, we can follow these steps: ### Step 1: Identify the Structure of Butane-2,3-diol Butane-2,3-diol has the following structure: ``` CH3 | CH3-CHOH-CHOH-CH3 ``` This compound has two chiral centers at the second and third carbon atoms. ### Step 2: Determine the Number of Stereoisomers The formula to calculate the maximum number of stereoisomers for a compound with 'n' chiral centers is given by \(2^n\). In the case of butane-2,3-diol: - n = 2 (since there are 2 chiral centers) Using the formula: \[ \text{Number of stereoisomers} = 2^n = 2^2 = 4 \] ### Step 3: Identify the Meso Compound Among the four stereoisomers, we need to identify if any of them are meso compounds. A meso compound has multiple stereocenters but is superimposable on its mirror image, making it optically inactive. For butane-2,3-diol, one of the stereoisomers is a meso compound. This means we have: - 1 meso compound (optically inactive) - 2 other stereoisomers that are optically active (D and L forms) ### Step 4: Conclusion Thus, the total number of optically active stereoisomers for butane-2,3-diol is: - 2 (D and L forms) ### Final Answer The answer is **2** optically active stereoisomers. ---

To determine how many optically active stereoisomers are possible for butane-2,3-diol, we can follow these steps: ### Step 1: Identify the Structure of Butane-2,3-diol Butane-2,3-diol has the following structure: ``` CH3 | ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. The compound which does not exhibit optical isomerism is

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  2. The correct statements about the compounds A, B and C is

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  3. How many optically active stereoisomers are possible for butane-2, 3-d...

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  4. During debromination of meso-dibromobutane, the major compound formed ...

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  5. Which one of the following compounds will show geometrical isomerism ?

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  6. Out of the following, the alkene that exhibits optical isomerism is ...

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  7. Identify the compound that exhibits tautomerism: 2-butene lactic...

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  8. How many chiral compounds are possible on monochlorination of 2-methyl...

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  9. Which branched chain isomer of the hydrocarbon with molecular mass 72u...

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  10. Which of the following acids does not exhibit optical isomerism?

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  11. Lassaigne's test is used in the qualitative analysis to detect

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  12. A compound which does not give positive test for nitrogen is: urea ...

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  13. For detection of sulphur in an organic compound, sodium nitroprusside ...

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  14. In sodium fusion test of organic compounds, the nitrogen of an organic...

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  15. The Beilstein test for organic compounds is used to detect

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  16. In the Duma's method for estimating nitrogen in an organic compound, t...

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  17. In Kjeldahl's method, nitrogen present is estimated as

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  18. Carbon and hydrogen are estimated by

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  19. A compound containing 80% C and 20% H is likely to be: C6 H6 C2 H6...

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  20. An organic compound is found to contain C - 40%. 0 = 53.34% and H = 6....

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