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Out of the following, the alkene that ex...

Out of the following, the alkene that exhibits optical isomerism is
3-methyl-2-pentene
4-methyl-1-pentene
3-methyl-1-pentene
2-methyl-2-pentene

A

3-methyl-2-pentene

B

4-methyl-1-pentene

C

3-methyl-1-pentene

D

2-methyl-2-pentene

Text Solution

AI Generated Solution

The correct Answer is:
To determine which alkene exhibits optical isomerism, we will analyze each of the given compounds for the presence of chiral centers. A chiral center is typically a carbon atom that is bonded to four different groups. ### Step-by-step Solution: 1. **Identify the Structures of Each Alkene:** - **3-methyl-2-pentene:** - Structure: CH3-CH(CH3)-CH=CH-CH3 - The double bond is between the second and third carbon atoms. - **4-methyl-1-pentene:** - Structure: CH2=CH-CH2-CH(CH3)-CH3 - The double bond is between the first and second carbon atoms. - **3-methyl-1-pentene:** - Structure: CH2=CH-CH(CH3)-CH2-CH3 - The double bond is between the first and second carbon atoms. - **2-methyl-2-pentene:** - Structure: CH3-C(CH3)=CH-CH3 - The double bond is between the second and third carbon atoms. 2. **Check for Chiral Centers:** - **3-methyl-2-pentene:** - No carbon has four different substituents. Thus, it has no chiral centers. - **4-methyl-1-pentene:** - No carbon has four different substituents. Thus, it has no chiral centers. - **3-methyl-1-pentene:** - The third carbon (C3) has four different groups: CH3, H, CH2, and CH=CH2. Thus, it has one chiral center. - **2-methyl-2-pentene:** - The second carbon (C2) has two identical methyl groups (CH3) attached. Thus, it has no chiral centers. 3. **Conclusion:** - The only alkene that exhibits optical isomerism due to the presence of a chiral center is **3-methyl-1-pentene**. ### Final Answer: The alkene that exhibits optical isomerism is **3-methyl-1-pentene**.

To determine which alkene exhibits optical isomerism, we will analyze each of the given compounds for the presence of chiral centers. A chiral center is typically a carbon atom that is bonded to four different groups. ### Step-by-step Solution: 1. **Identify the Structures of Each Alkene:** - **3-methyl-2-pentene:** - Structure: CH3-CH(CH3)-CH=CH-CH3 - The double bond is between the second and third carbon atoms. ...
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