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In the Duma's method for estimating nitr...

In the Duma's method for estimating nitrogen in an organic compound, the gas finally collected is

A

`N_2`

B

`NO`

C

`NH_3`

D

None of these

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The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding Dumas Method**: The Dumas method is a technique used to determine the nitrogen content in organic compounds. It involves the combustion of the organic sample in the presence of copper oxide. 2. **Combustion Reaction**: When the organic compound is heated with copper oxide, it undergoes oxidation. The general reaction can be represented as: \[ \text{Organic Compound} + \text{CuO} \rightarrow \text{N}_2 + \text{CO}_2 + \text{H}_2\text{O} \] Here, nitrogen gas (N₂), carbon dioxide (CO₂), and water (H₂O) are produced. 3. **Collection of Gases**: After the reaction, the gases produced are collected. The carbon dioxide and water vapor are absorbed using potassium hydroxide (KOH), which leaves behind nitrogen gas. 4. **Final Collection**: The only gas that remains unabsorbed and is collected is nitrogen gas (N₂). 5. **Estimation of Nitrogen**: The weight of the nitrogen gas collected is then used to calculate the percentage of nitrogen in the original organic compound. 6. **Conclusion**: Therefore, the gas finally collected in Dumas method for estimating nitrogen in an organic compound is nitrogen gas (N₂). **Final Answer**: The correct option is **A) Nitrogen (N₂)**. ---

**Step-by-Step Solution:** 1. **Understanding Dumas Method**: The Dumas method is a technique used to determine the nitrogen content in organic compounds. It involves the combustion of the organic sample in the presence of copper oxide. 2. **Combustion Reaction**: When the organic compound is heated with copper oxide, it undergoes oxidation. The general reaction can be represented as: \[ \text{Organic Compound} + \text{CuO} \rightarrow \text{N}_2 + \text{CO}_2 + \text{H}_2\text{O} \] ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. In sodium fusion test of organic compounds, the nitrogen of an organic...

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  2. The Beilstein test for organic compounds is used to detect

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  3. In the Duma's method for estimating nitrogen in an organic compound, t...

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  4. In Kjeldahl's method, nitrogen present is estimated as

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  5. Carbon and hydrogen are estimated by

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  6. A compound containing 80% C and 20% H is likely to be: C6 H6 C2 H6...

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  7. An organic compound is found to contain C - 40%. 0 = 53.34% and H = 6....

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  8. An organic compound has an empirical formula CH2 O. Its vapour density...

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  9. The empirical formula of a compound is CH2. One mole of this compound ...

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  10. The concentration of C = 85.45%, and H = 14.44% is not obeyed by the f...

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  11. If two compounds have the same empirical formula but different molecul...

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  12. 0.759 g of a silver salt of a dibasic organic acid on ignition gave 0....

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  13. 0.400 g of chloroplatinate salt of a monoacid base on ignition gave 0....

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  14. 0.500 g of the silver salt of an organic dibasic acid on ignition give...

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  15. In a Victor Meyer's determination of molecular mass, 0.1015 g of an or...

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  16. 0.29 g of an organic compound on combustion gave 0.66 g of CO2 and 0.2...

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  17. The blue compound formed in the positive test for nitrogen with Lassai...

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  18. The ammonia evolved from the treatment of 0.30 g of an organic compoun...

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  19. An organic compound having molecular mass 60 is found to contain C = 2...

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  20. The blue compound formed in the positive test for nitrogen with Lassai...

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