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In a free radical, the carbon atom carry...

In a free radical, the carbon atom carrying unpaired electron is

A

sp hybridised

B

`sp^2` hybridised

C

`sp^3` hybridised

D

`dsp^2` hybridised

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The correct Answer is:
To determine the hybridization of the carbon atom carrying an unpaired electron in a free radical, we can follow these steps: ### Step 1: Understand the Structure of a Free Radical A free radical is a species that contains an unpaired electron. In organic chemistry, free radicals often involve carbon atoms that have three bonds and one unpaired electron. ### Step 2: Identify the Hybridization of Carbon The hybridization of a carbon atom can be determined based on the number of bonds it forms: - **sp hybridization**: 2 bond pairs (linear geometry) - **sp2 hybridization**: 3 bond pairs (trigonal planar geometry) - **sp3 hybridization**: 4 bond pairs (tetrahedral geometry) - **dsp2 hybridization**: 4 bond pairs with a d orbital involved (not common for carbon) ### Step 3: Analyze the Free Radical In a free radical, the carbon atom typically forms three bonds (either with hydrogen atoms or other carbon atoms). This means that the carbon atom is involved in three bond pairs. ### Step 4: Determine the Hybridization Since the carbon atom in the free radical forms three bonds, it will undergo **sp2 hybridization**. The remaining p orbital, which is unhybridized, will contain the unpaired electron. ### Step 5: Conclusion Thus, the carbon atom carrying the unpaired electron in a free radical is **sp2 hybridized**. ### Final Answer The correct answer is **sp2 hybridized**. ---

To determine the hybridization of the carbon atom carrying an unpaired electron in a free radical, we can follow these steps: ### Step 1: Understand the Structure of a Free Radical A free radical is a species that contains an unpaired electron. In organic chemistry, free radicals often involve carbon atoms that have three bonds and one unpaired electron. ### Step 2: Identify the Hybridization of Carbon The hybridization of a carbon atom can be determined based on the number of bonds it forms: - **sp hybridization**: 2 bond pairs (linear geometry) ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. The number of electrons present in the valence shell of carbon bearing...

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  2. The compound which gives the most stable carbonium ion on dehydration ...

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  3. In a free radical, the carbon atom carrying unpaired electron is

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  4. Nitration of benzene is

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  5. The reaction intermediates involved in the addition of HBr to propene ...

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  6. The shape of carbanion [CH(3)]^(-) is: linear bent pyramidal ...

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  7. Which of the following is an electrophile ? NH3 AlCl3 OH^(-) CH3-O...

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  8. Heterolytic fission of C—Cl bond produces two free radicals two ca...

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  9. Which one of the following is the strongest acid ?

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  10. The most stable free radical is

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  11. The formation of cyanohydrin from a ketone is an example of nucleophi...

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  12. Which of the following alkyl halides is hydrolysed by S(N^1)mechanism ...

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  13. Which of the following does contain three pairs of electrons ?

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  14. Amongst the following, which are true for S(N^2) reaction ? (i) The ra...

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  15. Nucleophiles are while electrophiles are .

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  16. The + l-effect is shown by

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  17. Wilkinson's catalyst is

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  18. The hardness of water is estimated by (a)conductivity method (b)EDT...

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  19. Which of the following is an organometallic compound ?

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  20. Which of the following is an organometallic compound ?

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