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The + l-effect is shown by...

The + l-effect is shown by

A

`CH_3`

B

`-OH`

C

`F`

D

`-C_6 H_5`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which groups exhibit the +I (positive inductive) effect, we need to understand the concept of inductive effects in organic chemistry. The inductive effect is the permanent effect of the polarization of the electron density along a chain of atoms in a molecule due to the electronegativity differences between atoms. ### Step-by-Step Solution: 1. **Understanding Inductive Effect**: - The inductive effect can be classified into two types: +I effect (electron-donating) and -I effect (electron-withdrawing). - The +I effect occurs when a group has lower electronegativity than the carbon atom it is attached to, resulting in the donation of electron density towards the carbon chain. 2. **Identifying Groups**: - Consider the groups provided in the question: - CH3 (methyl group) - OH (hydroxyl group) - F (fluorine) - Phenyl group (C6H5) 3. **Analyzing Each Group**: - **CH3 (Methyl Group)**: - Carbon in CH3 has the same electronegativity as the carbon in the chain. Therefore, it donates electron density to the carbon chain, exhibiting a +I effect. - **OH (Hydroxyl Group)**: - Oxygen is more electronegative than carbon, which means it pulls electron density away from the carbon chain. Thus, it exhibits a -I effect. - **F (Fluorine)**: - Fluorine is highly electronegative compared to carbon, so it also withdraws electron density from the carbon chain, showing a -I effect. - **Phenyl Group (C6H5)**: - The sp2 hybridized carbon in the phenyl group is more electronegative than the sp3 hybridized carbon in the chain, resulting in a -I effect as it withdraws electron density. 4. **Conclusion**: - Among the groups analyzed, only the CH3 (methyl group) exhibits the +I effect. Therefore, the correct answer to the question is CH3. ### Final Answer: The +I effect is shown by the CH3 (methyl) group.

To determine which groups exhibit the +I (positive inductive) effect, we need to understand the concept of inductive effects in organic chemistry. The inductive effect is the permanent effect of the polarization of the electron density along a chain of atoms in a molecule due to the electronegativity differences between atoms. ### Step-by-Step Solution: 1. **Understanding Inductive Effect**: - The inductive effect can be classified into two types: +I effect (electron-donating) and -I effect (electron-withdrawing). - The +I effect occurs when a group has lower electronegativity than the carbon atom it is attached to, resulting in the donation of electron density towards the carbon chain. ...
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