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Which of the following is an organometal...

Which of the following is an organometallic compound ?

A

`Ti (C_2 H_5 )_4`

B

`Ti (OC_2 H_5)`

C

`Ti (OCOCH_3)_4`

D

`Ti (OC_6 H_5)_4`.

Text Solution

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The correct Answer is:
To determine which of the given compounds is an organometallic compound, we need to identify if there is a covalent bond between a carbon atom and a metal atom in each of the options provided. ### Step-by-Step Solution: 1. **Understanding Organometallic Compounds**: - Organometallic compounds are defined as compounds that contain at least one bond between a carbon atom and a metal atom. 2. **Analyzing the Options**: - **Option 1: Ti-C2H5-4** - In this compound, titanium (Ti) is bonded to four ethyl (C2H5) groups. Here, there is a direct covalent bond between the carbon atoms of the ethyl groups and the titanium atom. Therefore, this qualifies as an organometallic compound. - **Option 2: Ti-OC2H5-4** - In this compound, titanium is bonded to an oxygen atom (O) which is then bonded to the ethyl group (C2H5). Since the bond between titanium and the ethyl group is through an oxygen atom, this does not qualify as an organometallic compound. - **Option 3: Ti-OCOCH3-4** - Here, titanium is bonded to an oxygen atom, which is further bonded to an acetyl group (COCH3). Similar to the previous option, the bond between titanium and the carbon of the acetyl group is through an oxygen atom, so this is not an organometallic compound. - **Option 4: Ti-OC6H5-4** - In this case, titanium is bonded to an oxygen atom, which is then bonded to a phenyl group (C6H5). Again, the bond is through oxygen, meaning this does not qualify as an organometallic compound. 3. **Conclusion**: - After analyzing all the options, we find that only **Option 1: Ti-C2H5-4** has a direct covalent bond between carbon and titanium. Therefore, the correct answer is **Option 1**. ### Final Answer: **The organometallic compound is Option 1: Ti-C2H5-4.**

To determine which of the given compounds is an organometallic compound, we need to identify if there is a covalent bond between a carbon atom and a metal atom in each of the options provided. ### Step-by-Step Solution: 1. **Understanding Organometallic Compounds**: - Organometallic compounds are defined as compounds that contain at least one bond between a carbon atom and a metal atom. 2. **Analyzing the Options**: ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
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  2. Which of the following is an organometallic compound ?

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  3. Which of the following is an organometallic compound ?

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  4. In the compound, lithium tetrahydroaluminate, the ligand is

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  5. Which of the following ligands does form a chelate ?

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  6. The geometry of Ni(CO)4 and Ni(PPh3)Cl2 are

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  7. Ferrocene is described by the formula

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  8. Which of the following species is a carbene?

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  9. In a triplet carbene, the central carbon atom

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  10. Which of the following species does act as an electrophile ?

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  11. The reaction, RX + OH^(-) to R-OH + X^(-), is

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  12. The reaction CH3 Br + OH^(-) → CH3 OH + Br^(-) follows

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  13. An S(N^2) reaction occurs through the formation of a

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  14. The reaction, CH4+Cl2 overset("hv") to , CH3 Cl+HCl, occurs through

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  15. Which of the following acts as a nucleophile?

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  16. Which of the following has the highest nucleophilicity ? F^(-) OH^...

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  17. The order of reactivities of the following alkyl halides for an S(N^2)...

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  18. Following reaction, (CH3)3 CBr +H2O to (CH3)3 COH +HBr is an ...

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  19. Due to the presence of an unpaired electron, free radicals are

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  20. The organic chloro compound, which shows complete stereochemical inve...

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