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Which of the following ligands does form...

Which of the following ligands does form a chelate ?

A

Acetate

B

Oxalate

C

Cyanide

D

Ammonia

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The correct Answer is:
To determine which ligand forms a chelate, we need to understand the concept of chelation and the types of ligands involved. ### Step-by-Step Solution: 1. **Understand Chelation**: Chelation refers to the formation of a complex where a ligand binds to a metal ion at multiple points, forming a ring structure. These ligands are typically bidentate or polydentate. 2. **Identify the Types of Ligands**: - **Monodentate Ligands**: These ligands can bind to a metal ion at only one site. Examples include acetate (CH3COO-), cyanide (CN-), and ammonia (NH3). - **Bidentate Ligands**: These ligands can bind to a metal ion at two sites, allowing for the formation of a chelate. An example is oxalate (C2O4^2-). 3. **Analyze the Given Ligands**: - **Acetate (CH3COO-)**: This is a monodentate ligand as it can only bind through one oxygen atom. - **Oxalate (C2O4^2-)**: This is a bidentate ligand as it can bind through two oxygen atoms. - **Cyanide (CN-)**: This is a monodentate ligand as it can only bind through the carbon atom. - **Ammonia (NH3)**: This is also a monodentate ligand as it can only bind through the nitrogen atom. 4. **Determine Which Ligands Form Chelates**: - From the analysis, only oxalate is a bidentate ligand that can form a chelate. The other ligands (acetate, cyanide, and ammonia) are monodentate and do not form chelates. 5. **Conclusion**: The ligand that forms a chelate among the given options is **oxalate (C2O4^2-)**. ### Final Answer: The ligand that forms a chelate is **oxalate (C2O4^2-)**.

To determine which ligand forms a chelate, we need to understand the concept of chelation and the types of ligands involved. ### Step-by-Step Solution: 1. **Understand Chelation**: Chelation refers to the formation of a complex where a ligand binds to a metal ion at multiple points, forming a ring structure. These ligands are typically bidentate or polydentate. 2. **Identify the Types of Ligands**: - **Monodentate Ligands**: These ligands can bind to a metal ion at only one site. Examples include acetate (CH3COO-), cyanide (CN-), and ammonia (NH3). ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. Which of the following is an organometallic compound ?

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  2. In the compound, lithium tetrahydroaluminate, the ligand is

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  3. Which of the following ligands does form a chelate ?

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  4. The geometry of Ni(CO)4 and Ni(PPh3)Cl2 are

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  5. Ferrocene is described by the formula

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  6. Which of the following species is a carbene?

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  7. In a triplet carbene, the central carbon atom

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  8. Which of the following species does act as an electrophile ?

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  9. The reaction, RX + OH^(-) to R-OH + X^(-), is

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  10. The reaction CH3 Br + OH^(-) → CH3 OH + Br^(-) follows

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  11. An S(N^2) reaction occurs through the formation of a

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  12. The reaction, CH4+Cl2 overset("hv") to , CH3 Cl+HCl, occurs through

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  13. Which of the following acts as a nucleophile?

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  14. Which of the following has the highest nucleophilicity ? F^(-) OH^...

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  15. The order of reactivities of the following alkyl halides for an S(N^2)...

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  16. Following reaction, (CH3)3 CBr +H2O to (CH3)3 COH +HBr is an ...

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  17. Due to the presence of an unpaired electron, free radicals are

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  18. The organic chloro compound, which shows complete stereochemical inve...

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  19. Which one is a nucleophilic substitution reaction among the following ...

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  20. The order of stability of the following carbocations CH2 = underset...

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