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In a triplet carbene, the central carbon...

In a triplet carbene, the central carbon atom

A

is `sp^2` hybridised

B

contains a lone pair of electrons

C

forms one o and one bonds with the groups attached

D

contains two unpaired electrons.

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The correct Answer is:
To solve the question regarding the characteristics of a triplet carbene, we will analyze the properties of the central carbon atom in this species. ### Step-by-Step Solution: 1. **Understanding Triplet Carbene**: - A triplet carbene is a species that contains a carbon atom with two unpaired electrons. This gives it a total spin multiplicity of three, hence the term "triplet." 2. **Hybridization of the Central Carbon Atom**: - In a triplet carbene, the central carbon atom is **sp² hybridized**. This means that one s orbital and two p orbitals mix to form three sp² hybrid orbitals. 3. **Bond Formation**: - The sp² hybridization allows the carbon atom to form: - **One sigma bond** with each of the two groups (e.g., hydrogen atoms) attached to it. - The remaining unhybridized p orbital contains one unpaired electron. 4. **Electron Configuration**: - The two unpaired electrons in the triplet carbene are located in the two unhybridized p orbitals. This configuration leads to the characteristic stability and reactivity of carbenes. 5. **Conclusion**: - Therefore, in a triplet carbene, the central carbon atom is sp² hybridized, contains **two unpaired electrons**, and forms **two sigma bonds** with the groups attached to it, while the unhybridized p orbitals hold the unpaired electrons. ### Final Answer: In a triplet carbene, the central carbon atom is sp² hybridized, contains two unpaired electrons, and forms one sigma bond with each of the groups attached. ---

To solve the question regarding the characteristics of a triplet carbene, we will analyze the properties of the central carbon atom in this species. ### Step-by-Step Solution: 1. **Understanding Triplet Carbene**: - A triplet carbene is a species that contains a carbon atom with two unpaired electrons. This gives it a total spin multiplicity of three, hence the term "triplet." 2. **Hybridization of the Central Carbon Atom**: ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. Ferrocene is described by the formula

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  2. Which of the following species is a carbene?

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  3. In a triplet carbene, the central carbon atom

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  4. Which of the following species does act as an electrophile ?

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  5. The reaction, RX + OH^(-) to R-OH + X^(-), is

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  6. The reaction CH3 Br + OH^(-) → CH3 OH + Br^(-) follows

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  7. An S(N^2) reaction occurs through the formation of a

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  8. The reaction, CH4+Cl2 overset("hv") to , CH3 Cl+HCl, occurs through

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  9. Which of the following acts as a nucleophile?

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  10. Which of the following has the highest nucleophilicity ? F^(-) OH^...

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  11. The order of reactivities of the following alkyl halides for an S(N^2)...

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  12. Following reaction, (CH3)3 CBr +H2O to (CH3)3 COH +HBr is an ...

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  13. Due to the presence of an unpaired electron, free radicals are

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  14. The organic chloro compound, which shows complete stereochemical inve...

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  15. Which one is a nucleophilic substitution reaction among the following ...

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  16. The order of stability of the following carbocations CH2 = underset...

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  17. The correct statement regarding electrophile is

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  18. The most suitable method of separation of 1:1 mixture of ortho and par...

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  19. Identify A and predict the type of reaction

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  20. The IUPAC name of the compound

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