Home
Class 11
CHEMISTRY
The reaction CH3 Br + OH^(-) → CH3 OH + ...

The reaction `CH_3 Br + OH^(-) → CH_3 OH + Br^(-)` follows

A

`S_(N^1)` mechanism

B

`S_(N^2)`mechanism

C

either of the above two

D

none of the above two

Text Solution

AI Generated Solution

The correct Answer is:
To determine the mechanism of the reaction \( \text{CH}_3 \text{Br} + \text{OH}^- \rightarrow \text{CH}_3 \text{OH} + \text{Br}^- \), we need to analyze the nature of the reactants and the mechanism of nucleophilic substitution. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are methyl bromide (\( \text{CH}_3 \text{Br} \)) and hydroxide ion (\( \text{OH}^- \)). 2. **Determine the Type of Alkyl Halide**: Methyl bromide (\( \text{CH}_3 \text{Br} \)) is a primary alkyl halide. Primary alkyl halides are those where the carbon atom bonded to the halogen is attached to only one other carbon atom. 3. **Understand the Nucleophile**: The hydroxide ion (\( \text{OH}^- \)) is a strong nucleophile. Nucleophiles are species that donate an electron pair to form a chemical bond. 4. **Consider the Mechanisms**: There are two main mechanisms for nucleophilic substitution: - **SN1 Mechanism**: This involves the formation of a carbocation intermediate and is favored by tertiary alkyl halides. - **SN2 Mechanism**: This involves a direct attack by the nucleophile on the carbon atom, leading to a transition state and is favored by primary alkyl halides. 5. **Analyze the Mechanism for \( \text{CH}_3 \text{Br} \)**: Since \( \text{CH}_3 \text{Br} \) is a primary alkyl halide, it will undergo the SN2 mechanism. In this mechanism, the nucleophile (\( \text{OH}^- \)) attacks the carbon atom from the opposite side of the leaving group (bromide ion, \( \text{Br}^- \)). 6. **Transition State Formation**: As the nucleophile attacks, a transition state is formed where the bond between the carbon and bromine is partially broken while the bond between the carbon and oxygen is partially formed. 7. **Final Product Formation**: The reaction results in the formation of methanol (\( \text{CH}_3 \text{OH} \)) and bromide ion (\( \text{Br}^- \)). The configuration of the product is inverted due to the backside attack characteristic of the SN2 mechanism. ### Conclusion: The reaction \( \text{CH}_3 \text{Br} + \text{OH}^- \rightarrow \text{CH}_3 \text{OH} + \text{Br}^- \) follows the **SN2 mechanism**. ---

To determine the mechanism of the reaction \( \text{CH}_3 \text{Br} + \text{OH}^- \rightarrow \text{CH}_3 \text{OH} + \text{Br}^- \), we need to analyze the nature of the reactants and the mechanism of nucleophilic substitution. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are methyl bromide (\( \text{CH}_3 \text{Br} \)) and hydroxide ion (\( \text{OH}^- \)). 2. **Determine the Type of Alkyl Halide**: ...
Promotional Banner

Topper's Solved these Questions

  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    ICSE|Exercise TRUE OR FALSE TYPE QUESTIONS|50 Videos
  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    ICSE|Exercise FILL IN THE BLANK TYPE QUESTIONS |46 Videos
  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    ICSE|Exercise ESSAY ( LONG ANSWER ) TYPE QUESTIONS|42 Videos
  • HYDROGEN

    ICSE|Exercise NCERT TEXT-BOOK EXERCISE (With Hints and Solutions)|53 Videos
  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise NCERT TEXT-BOOK. EXERCISES ((With Hints and Solutions)|69 Videos

Similar Questions

Explore conceptually related problems

The reaction , CH_(3)Br +OH^(-)rarrCH_(3)OH+Br^(-) obeys the mechanism

The reaction : CH_3 CH_2 l + KOH(aq) to CH_3 CH_2 OH +Kl is classified as

In the reaction Bromine 3Br_2 + 6 OH^(-) rarr 5 Br ^(-) + BrO_3^(-) + 3H_2O

Classify the following reactions in one of the reaction type studied in this unit. CH_3CH_2 Br + HO^(-) to CH_2 = CH_2 +H_2 O + Br^(-)

Predict the order of reactivity of the following compounds in dehydrohalogenation : CH_3 CH (Br) CH_3, CH_3 CH_2 CH_2 Br, (CH_3)_2 - CH - CH_2Br, (CH_2)_3C - CH_2 Br .

Consider the following reactions : (a) ( CH _ 3) _ 3 CCH ( OH ) CH_ 3 overset ( conc. H_ 2 SO _ 4) to (b) ( CH _ 3) _ 2CHCH (Br) CH _ 3 ( alc. KOH) to (c ) ( CH _ 3 ) _ 2 CH CH ( Br ) CH _ 3 ( (CH _ 3) _ 3 ) O^(Theta) K (o+)) to (d) (CH _ 3) _ 2 underset(OH) underset(|) C - CH _ 2 - CHO overset ( Delta ) to Which of these reaction (s) will not produce Saytzeff product ?

Arrange the following compounds in increasing order of S_(N^1) reactivity. CH_3 CH_2 Br, CH_2 = CH CH (Br) CH_3, CH_3 CH (Br) CH_3

ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. Which of the following species does act as an electrophile ?

    Text Solution

    |

  2. The reaction, RX + OH^(-) to R-OH + X^(-), is

    Text Solution

    |

  3. The reaction CH3 Br + OH^(-) → CH3 OH + Br^(-) follows

    Text Solution

    |

  4. An S(N^2) reaction occurs through the formation of a

    Text Solution

    |

  5. The reaction, CH4+Cl2 overset("hv") to , CH3 Cl+HCl, occurs through

    Text Solution

    |

  6. Which of the following acts as a nucleophile?

    Text Solution

    |

  7. Which of the following has the highest nucleophilicity ? F^(-) OH^...

    Text Solution

    |

  8. The order of reactivities of the following alkyl halides for an S(N^2)...

    Text Solution

    |

  9. Following reaction, (CH3)3 CBr +H2O to (CH3)3 COH +HBr is an ...

    Text Solution

    |

  10. Due to the presence of an unpaired electron, free radicals are

    Text Solution

    |

  11. The organic chloro compound, which shows complete stereochemical inve...

    Text Solution

    |

  12. Which one is a nucleophilic substitution reaction among the following ...

    Text Solution

    |

  13. The order of stability of the following carbocations CH2 = underset...

    Text Solution

    |

  14. The correct statement regarding electrophile is

    Text Solution

    |

  15. The most suitable method of separation of 1:1 mixture of ortho and par...

    Text Solution

    |

  16. Identify A and predict the type of reaction

    Text Solution

    |

  17. The IUPAC name of the compound

    Text Solution

    |

  18. Which of the following is correct with respect to -|-effect of the sub...

    Text Solution

    |

  19. Which of the following carbocations is expected to be most stable?

    Text Solution

    |

  20. Which of the following compounds will be suitable for Kjeldahl's metho...

    Text Solution

    |