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Following reaction, (CH3)3 CBr +H2O to...

Following reaction,
`(CH_3)_3 CBr +H_2O to (CH_3)_3 COH +HBr ` is an example of
elimination reaction
free radical substitution
nucleophilic substitution
electrophilic substitution.

A

elimination reaction

B

free radical substitution

C

nucleophilic substitution

D

electrophilic substitution.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction `(CH₃)₃CBr + H₂O → (CH₃)₃COH + HBr`, we need to analyze the nature of the reaction taking place. Here’s a step-by-step breakdown: ### Step 1: Identify the Reactants and Products The reactants are tert-butyl bromide `(CH₃)₃CBr` and water `H₂O`. The products are tert-butyl alcohol `(CH₃)₃COH` and hydrogen bromide `HBr`. **Hint:** Look for the functional groups in the reactants and products to understand what changes are occurring. ### Step 2: Determine the Type of Reaction In the given reaction, the bromine atom (Br) in tert-butyl bromide is replaced by a hydroxyl group (OH) from water. This indicates that a substitution is taking place. **Hint:** Identify whether atoms or groups are being replaced or removed to classify the reaction. ### Step 3: Classify the Reaction Since Br is being replaced by OH, this is a substitution reaction. We need to determine if it is nucleophilic or electrophilic. In this case, the hydroxide ion (OH⁻) acts as a nucleophile, attacking the carbon atom that is bonded to the bromine. **Hint:** Remember that nucleophiles donate electrons, while electrophiles accept them. ### Step 4: Eliminate Other Options - **Elimination Reaction:** This involves the removal of atoms or groups from a molecule, which is not happening here. - **Free Radical Substitution:** This typically involves the substitution of atoms in the presence of free radicals, which is not applicable in this case. - **Electrophilic Substitution:** This involves an electrophile attacking a nucleophile, which is not the case here since OH⁻ is the nucleophile. **Hint:** Cross out options that do not fit the mechanism of the reaction. ### Step 5: Conclude the Type of Reaction Since the reaction involves the nucleophilic attack of OH⁻ on the carbocation formed after the departure of Br, it is classified as a **nucleophilic substitution reaction**. More specifically, it is an **SN1 reaction** (unimolecular nucleophilic substitution) because it involves the formation of a carbocation intermediate. **Final Answer:** The reaction `(CH₃)₃CBr + H₂O → (CH₃)₃COH + HBr` is an example of **nucleophilic substitution**.

To solve the question regarding the reaction `(CH₃)₃CBr + H₂O → (CH₃)₃COH + HBr`, we need to analyze the nature of the reaction taking place. Here’s a step-by-step breakdown: ### Step 1: Identify the Reactants and Products The reactants are tert-butyl bromide `(CH₃)₃CBr` and water `H₂O`. The products are tert-butyl alcohol `(CH₃)₃COH` and hydrogen bromide `HBr`. **Hint:** Look for the functional groups in the reactants and products to understand what changes are occurring. ### Step 2: Determine the Type of Reaction ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
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  2. The order of reactivities of the following alkyl halides for an S(N^2)...

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  3. Following reaction, (CH3)3 CBr +H2O to (CH3)3 COH +HBr is an ...

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  4. Due to the presence of an unpaired electron, free radicals are

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  5. The organic chloro compound, which shows complete stereochemical inve...

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  6. Which one is a nucleophilic substitution reaction among the following ...

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  7. The order of stability of the following carbocations CH2 = underset...

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  8. The correct statement regarding electrophile is

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  9. The most suitable method of separation of 1:1 mixture of ortho and par...

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  10. Identify A and predict the type of reaction

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  11. The IUPAC name of the compound

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  12. Which of the following is correct with respect to -|-effect of the sub...

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  13. Which of the following carbocations is expected to be most stable?

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  15. The number of sigma (sigma ) and pi (pi) bonds in pent-2-en-4-yne is :

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  16. The IUPAC name for the following compound is :

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  17. Increasing order of reactivity of the following compounds for S(N^1) s...

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  18. Which of the following is potential energy diagram for S(N)1 reaction?

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  19. The correct IUPAC name of the following compound is :

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  20. The IUPAC name of the following compound is: H(3)C-overset(CH(3))ove...

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