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For the reaction, NH4Cl(s) to NH3(g) + H...

For the reaction, `NH_4Cl(s) to NH_3(g) + HCl(g)` at `25^@C`, enthalpy change `DeltaH = + 177 kJ mol^(-1)` and entropy change `Delta S = + 285 J mol^(-1) K^(-1)`. Calculate the free energy change `DeltaG" at " 25^@C` and predict whether the reaction is spontaneous or not.

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To solve the problem, we need to calculate the free energy change (ΔG) for the reaction using the given values for enthalpy change (ΔH) and entropy change (ΔS). We will also determine if the reaction is spontaneous based on the value of ΔG. ### Step-by-Step Solution: 1. **Identify the given values:** - Enthalpy change (ΔH) = +177 kJ/mol - Entropy change (ΔS) = +285 J/(mol·K) - Temperature (T) = 25°C ...
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ICSE-CHEMICAL THERMODYNAMICS -NCERT TEXT-BOOK. EXERCISES
  1. For the reaction, NH4Cl(s) to NH3(g) + HCl(g) at 25^@C, enthalpy chang...

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  2. Choose the correct answer. A thermodynamic state function is a quanti...

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  3. For the process to occur under adiabatic conditions, the correct condi...

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  4. The enthalpies of all elements in their standard states are

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  5. DeltaU^@ of combustion of methane is -X kJ mol^(-1). The value of Delt...

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  6. The enthalpy of combustion of methane, graphite and dihydrogen at 298 ...

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  7. A reaction A + B toC + D + q is found to have a positive entropy chang...

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  8. In a process, 701 J of heat is absorbed by a system and 394 J of work ...

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  9. The reaction of cyanamide, NH(2)CN (s), with dioxygen was carried out ...

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  10. Calculate the number of kJ of heat necessary to raise the temperature ...

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  11. The enthalpy change on freezing of 1 mol of water at 5^(@)C to ice at ...

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  12. Enthalpy of combustion of carbon to CO2 is -393.5 kJ mol^(-1) Calcu...

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  13. Enthalpies of formation of CO(g).CO(2)(g) and N(2)O(4) are -110,-393,8...

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  14. Given N(2)(g)+3H(2)(g)rarr2NH(3)(g),Delta(r)H^(Ө)= -92.4 kJ mol^(-1...

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  15. Calculate the standard enthalpy of formation of CH(3)OH(l) from the fo...

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  16. Calculate the enthalpy change for the process C CI(4)(g)rarrC(g)+4C...

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  17. For an isolated system, DeltaU=0, what will be Delta S?

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  18. For the reaction at 298 K, 2A + B to C DeltaH=400 KJ mol^(-1) an...

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  19. For the reaction, 2Cl(g) to Cl2(g), what are the signs of DeltaH and D...

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  20. For the reaction 2A(g)+B(g)rarr2D(g) DeltaU^(theta)=-10.55 KJ and ...

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  21. The equilibrium constant for a reaction is 10. What will be the value ...

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