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The enthalpy change (DeltaH) for the rea...

The enthalpy change (`DeltaH`) for the reaction
`Ag_2O(s) hArr 2Ag(s) + 1/2 O_2(g)`
is `30.54 kJ mol^(-1)` and entropy change `(DeltaS)` is `0.06 kJ K^(-1) mol^(-1)` at 1 atm. Calculate the temperature at which `DeltaG` is equal to zero. Also predict the direction of reaction at a temperature below the calculated temperature.

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AI Generated Solution

To solve the problem, we need to calculate the temperature at which the Gibbs free energy change (ΔG) for the reaction is equal to zero. We will use the relationship between ΔG, ΔH, and ΔS, which is given by the equation: \[ \Delta G = \Delta H - T \Delta S \] ### Step 1: Set ΔG to zero Since we want to find the temperature at which ΔG = 0, we can set up the equation: ...
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ICSE-CHEMICAL THERMODYNAMICS -NCERT TEXT-BOOK. EXERCISES
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  2. Choose the correct answer. A thermodynamic state function is a quanti...

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  3. For the process to occur under adiabatic conditions, the correct condi...

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  4. The enthalpies of all elements in their standard states are

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  5. DeltaU^@ of combustion of methane is -X kJ mol^(-1). The value of Delt...

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  6. The enthalpy of combustion of methane, graphite and dihydrogen at 298 ...

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  7. A reaction A + B toC + D + q is found to have a positive entropy chang...

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  8. In a process, 701 J of heat is absorbed by a system and 394 J of work ...

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  9. The reaction of cyanamide, NH(2)CN (s), with dioxygen was carried out ...

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  10. Calculate the number of kJ of heat necessary to raise the temperature ...

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  11. The enthalpy change on freezing of 1 mol of water at 5^(@)C to ice at ...

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  12. Enthalpy of combustion of carbon to CO2 is -393.5 kJ mol^(-1) Calcu...

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  13. Enthalpies of formation of CO(g).CO(2)(g) and N(2)O(4) are -110,-393,8...

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  14. Given N(2)(g)+3H(2)(g)rarr2NH(3)(g),Delta(r)H^(Ө)= -92.4 kJ mol^(-1...

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  15. Calculate the standard enthalpy of formation of CH(3)OH(l) from the fo...

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  16. Calculate the enthalpy change for the process C CI(4)(g)rarrC(g)+4C...

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  17. For an isolated system, DeltaU=0, what will be Delta S?

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  18. For the reaction at 298 K, 2A + B to C DeltaH=400 KJ mol^(-1) an...

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  19. For the reaction, 2Cl(g) to Cl2(g), what are the signs of DeltaH and D...

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  20. For the reaction 2A(g)+B(g)rarr2D(g) DeltaU^(theta)=-10.55 KJ and ...

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  21. The equilibrium constant for a reaction is 10. What will be the value ...

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