Define enthalpy and enthalpy change. Show that `DeltaH = q_p`.

Enthalpy is

Define enthalpy of reaction.

In a reaction P+Q rarr R+S , there is no change in entropy, Enthalpy change for the reaction (DeltaH) is "12 kJ mol"^(-1) . Under what conditions, reaction will have negative value of free energy change?

Gibbs-Helmoholtz equation relates the free energy change to the enthalpy and entropy changes of the process as (DeltaG)_(PT) = DeltaH - T DeltaS The magnitude of DeltaH does not change much with the change in temperature but the enrgy factor T DeltaS changes appreciably. Thus, spontaneity of a process depends very much on temperature. For the reaction at 298K, 2A +B rarr C DeltaH = 100 kcal and DeltaS = 0.020 kcal K^(-1) . If DeltaH and DeltaS are assumed to be constant over the temperature range, at what temperature will the reaction become spontaneous?

Gibbs-Helmoholtz equation relates the free energy change to the enthalpy and entropy changes of the process as (DeltaG)_(PT) = DeltaH - T DeltaS The magnitude of DeltaH does not change much with the change in temperature but the enrgy factor T DeltaS changes appreciably. Thus, spontaneity of a process depends very much on temperature. The enthalpy change for a certain reaction at 300K is -15.0 kcal mol^(-1) . The entropy change under these conditions is -7.2 cal K^(-) mol^(-1) . The free enegry change for the reaction and its spontaneous//nonspontaneous character will be

Gibbs-Helmoholtz equation relates the free energy change to the enthalpy and entropy changes of the process as (DeltaG)_(PT) = DeltaH - T DeltaS The magnitude of DeltaH does not change much with the change in temperature but the energy factor T DeltaS changes appreciably. Thus, spontaneity of a process depends very much on temperature. A reaction has value of DeltaH = 20 kcal at 200K , the reaction is spontaneous, below this temperature, it is not. the values DeltaG and DeltaS at 200K are, respectively

Gibbs-Helmoholtz equation relates the free energy change to the enthalpy and entropy changes of the process as (DeltaG)_(PT) = DeltaH - T DeltaS The magnitude of DeltaH does not change much with the change in temperature but the energy factor T DeltaS changes appreciably. Thus, spontaneity of a process depends very much on temperature. For the reaction at 25^(0)C, X_(2)O_(4)(l) rarr 2XO_(2) DeltaH = 2.0 kcal and DeltaS = 20 cal K^(-1) . the reaction would be

Define internal energy and enthalpy of a system.

Define enthalpy. Show that the change in enthalpy at constant pressure for a reaction involving gases is given by the expression, DeltaH = DeltaU + Deltan_(g) .RT .

Enthalpy change equal internal energy change when