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During the isothermal expansion of an id...

During the isothermal expansion of an ideal gas, its
internal energy increases
enthalpy decreases
enthalpy remains unaffected
enthalpy reduces to zero.

A

internal energy increases

B

enthalpy decreases

C

enthalpy remains unaffected

D

enthalpy reduces to zero.

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The correct Answer is:
To solve the question regarding the behavior of internal energy and enthalpy during the isothermal expansion of an ideal gas, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Isothermal Process**: - An isothermal process is one in which the temperature (T) of the system remains constant throughout the process. For an ideal gas, this means that any energy added to the system as heat (Q) is used to do work (W) by the gas. 2. **Internal Energy of an Ideal Gas**: - The internal energy (U) of an ideal gas depends only on its temperature. Since the temperature is constant during an isothermal process, the change in internal energy (ΔU) is zero. - Mathematically, ΔU = 0 for an ideal gas in an isothermal process. 3. **Enthalpy Definition**: - Enthalpy (H) is defined as H = U + PV, where P is pressure and V is volume. The change in enthalpy (ΔH) can be expressed as: \[ \Delta H = \Delta U + \Delta(PV) \] 4. **Applying the Ideal Gas Law**: - According to the ideal gas law, PV = nRT, where n is the number of moles and R is the universal gas constant. Since T is constant during an isothermal process, the product PV also remains constant. - Therefore, Δ(PV) = 0. 5. **Calculate Change in Enthalpy**: - Since both ΔU = 0 and Δ(PV) = 0, we can conclude: \[ \Delta H = 0 + 0 = 0 \] - This indicates that the enthalpy does not change during the isothermal expansion. 6. **Conclusion**: - Based on the analysis, we can conclude that during the isothermal expansion of an ideal gas, the internal energy remains constant, and the enthalpy also remains unaffected (ΔH = 0). ### Final Answer: - **Enthalpy remains unaffected**.

To solve the question regarding the behavior of internal energy and enthalpy during the isothermal expansion of an ideal gas, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Isothermal Process**: - An isothermal process is one in which the temperature (T) of the system remains constant throughout the process. For an ideal gas, this means that any energy added to the system as heat (Q) is used to do work (W) by the gas. 2. **Internal Energy of an Ideal Gas**: ...
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ICSE-CHEMICAL THERMODYNAMICS -OBJECTIVE (MULTIPLE CHOCE) TYPE QUESTIONS
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  2. Thermodynamic equilibrium involves

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  3. During the isothermal expansion of an ideal gas, its internal energy...

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  9. In which of the following changes does entropy decrease ?

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  10. For which reaction among the following, is DeltaS maximum ?

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  11. The free energy change for a reversible reaction at equilibrium is: ...

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  12. The spontaneous nature of a reaction is impossible if

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  13. Which is an extensive property of the system? Temperature Volume ...

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  14. Which is not a state function of a thermodynamic system? Internal en...

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  15. Is the entropy of the universe constant ?

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  16. Decrease in free energy of a reacting system indicates: an exothermi...

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  17. Gibbs free energy G, enthalpy H and entropy S are related as

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  18. A system is provided 50 J of heat and work done on the system is 10 J...

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  19. The entropy change for vapourisation of liquid water to steam 100^@C i...

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