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The standard Gibbs energy for the given ...

The standard Gibbs energy for the given cell reaction in kJ `mol^(-1)` at 298 K is
`Zn(s) + Cu^(2+) (aq) to Zn^(2+)(aq) + Cu(s), E^@ = 2V " at " 298 K `
(Faraday's constant, `F = 96000 C mol^(-1)`)

A

`-192`

B

`192`

C

-384

D

384

Text Solution

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The correct Answer is:
To calculate the standard Gibbs energy (ΔG) for the given cell reaction at 298 K, we can use the following equation: \[ \Delta G = -nFE^0 \] Where: - \( \Delta G \) = Gibbs free energy change (in joules) - \( n \) = number of moles of electrons transferred in the reaction - \( F \) = Faraday's constant (in coulombs per mole) - \( E^0 \) = standard cell potential (in volts) ### Step-by-step Solution: 1. **Identify the number of electrons transferred (n)**: In the given reaction: \[ \text{Zn(s)} + \text{Cu}^{2+}(aq) \rightarrow \text{Zn}^{2+}(aq) + \text{Cu(s)} \] Zinc (Zn) is oxidized from 0 to +2, which means it loses 2 electrons. Copper (Cu) is reduced from +2 to 0, which means it gains 2 electrons. Therefore, \( n = 2 \). 2. **Identify the Faraday's constant (F)**: The problem states that \( F = 96000 \, \text{C mol}^{-1} \). 3. **Identify the standard cell potential (E^0)**: The standard cell potential is given as \( E^0 = 2 \, \text{V} \). 4. **Substitute the values into the Gibbs energy equation**: Now we can substitute \( n \), \( F \), and \( E^0 \) into the equation: \[ \Delta G = -nFE^0 = -2 \times 96000 \, \text{C mol}^{-1} \times 2 \, \text{V} \] 5. **Calculate ΔG**: \[ \Delta G = -2 \times 96000 \times 2 = -384000 \, \text{J} \] 6. **Convert ΔG from joules to kilojoules**: Since \( 1 \, \text{kJ} = 1000 \, \text{J} \): \[ \Delta G = -384000 \, \text{J} \div 1000 = -384 \, \text{kJ} \] ### Final Answer: The standard Gibbs energy for the given cell reaction at 298 K is: \[ \Delta G = -384 \, \text{kJ mol}^{-1} \]

To calculate the standard Gibbs energy (ΔG) for the given cell reaction at 298 K, we can use the following equation: \[ \Delta G = -nFE^0 \] Where: - \( \Delta G \) = Gibbs free energy change (in joules) ...
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