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We have three aqueous solutions of NaCl ...

We have three aqueous solutions of NaCl lebelled as'A' , 'B' and 'C' with concentrations 0.1 M, 0.01 M and 0.001 M respectively. The value of van't Hoff factor for these solution will be in the order……….

A

`i_(A) lt i_(B) lt i_(C )`

B

`i_(A) gt i_(B) gt i_(C )`

C

`i_(A)=i_(B)=i_(C )`

D

`i_(A) lt i_(B) gt i_(C )`

Text Solution

Verified by Experts

The correct Answer is:
C

NaCl being a strong electrolyte, ionizes completely in dilute solution `(alpha = 1)`. Therefore, the value of van.t Hoff factor does not change with the change in molar concentration of NaCl. Therefore, `i_(A) = i_(B) = i_(C )`.
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