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A white precipitate is formed when silve...

A white precipitate is formed when silver nitrate is added to a solution containing chloride ions. This precipitate is soluble in 
Hydrochloric acid ; Nitric acid ; Dilute H 2 S O 4 ; Ammonium hydroxide ;

A

Hydrochloric acid

B

Nitric acid

C

Dilute `H_2SO_4`

D

Ammonium hydroxide

Text Solution

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The correct Answer is:
To solve the question regarding the solubility of the white precipitate formed when silver nitrate is added to a solution containing chloride ions, we will follow these steps: ### Step 1: Identify the Reaction When silver nitrate (AgNO₃) is added to a solution containing chloride ions (Cl⁻), a white precipitate of silver chloride (AgCl) is formed. The reaction can be represented as follows: \[ \text{AgNO}_3 (aq) + \text{Cl}^- (aq) \rightarrow \text{AgCl} (s) + \text{NO}_3^- (aq) \] ### Step 2: Analyze the Precipitate The precipitate formed, silver chloride (AgCl), is known to be a white solid that is only sparingly soluble in water. We need to determine in which of the given solutions this precipitate is soluble. ### Step 3: Evaluate the Options 1. **Hydrochloric acid (HCl)**: Adding HCl would not dissolve AgCl, as it would simply provide more chloride ions, which would continue to form AgCl. 2. **Nitric acid (HNO₃)**: Similar to HCl, nitric acid does not dissolve AgCl because it does not provide a mechanism to break down the precipitate. The ions remain in solution but do not affect the precipitate. 3. **Dilute H₂SO₄**: Dilute sulfuric acid also does not dissolve AgCl. The solubility product constant (Ksp) for AgCl indicates that it remains insoluble in dilute acids. 4. **Ammonium hydroxide (NH₄OH)**: AgCl is soluble in ammonium hydroxide due to the formation of a complex ion. When AgCl is treated with ammonium hydroxide, it forms a soluble complex ion: \[ \text{AgCl} (s) + 2 \text{NH}_4\text{OH} (aq) \rightarrow [\text{Ag(NH}_3)_2]^+ (aq) + \text{Cl}^- (aq) + 2 \text{H}_2\text{O} (l) \] ### Step 4: Conclusion From the analysis above, we conclude that the white precipitate of silver chloride (AgCl) is soluble in ammonium hydroxide. ### Final Answer **Ammonium hydroxide** ---
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Knowledge Check

  • The colour of the precipitate formed when ferrous ions react with ammonium hydroxide solution

    A
    Blue
    B
    Reddish brown
    C
    Dirty green
    D
    White
  • A chloride which forms a precipitate that is soluble in excess of ammonium hydroxide is :

    A
    Calcium chloride
    B
    Ferrous chloride
    C
    Ferric chloride
    D
    Copper chloride
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