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State two relevant observations for each...

State two relevant observations for each of the following:
Ammonium hydroxide solution is added to zinc nitrate solution in minimum quantities and then in excess

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A white precipitate of Zinc hydroxide is obtained which dissolves in excess of the reagent forming a colourless solution due to the formation of soluble complex compound, Zinc tetra amine sulphate.
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State relevant observations for the following: Ammonium hydroxide solution is added to zinc nitrate solution in minimum quantity and thien in excess.

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