Home
Class 12
CHEMISTRY
An excess of liquid mercury is added to ...

An excess of liquid mercury is added to an acidicfied solution of `1.0xx10^(-3) M Fe^(3+)` . It is found that `5%` of `Fe^(3+)` remains at equilibrium at `25^(@)C`. Calculate `E^(c-)._((Hg_(2)^(2+)|Hg))` assuming that the only reaction that occurs is
`2Hg+2Fe^(3+) rarr Hg_(2)^(2+)+2Fe^(2+)`
Given `: E^(c-)._((Fe^(3+)|Fe^(2+)))=0.77V`

A

0.85 V

B

0.79 V

C

0.65 V

D

0.35 V

Text Solution

Verified by Experts

Promotional Banner

Topper's Solved these Questions

  • MOCK TEST 2

    KVPY PREVIOUS YEAR|Exercise EXERCISE|29 Videos
  • MOCK TEST 4

    KVPY PREVIOUS YEAR|Exercise EXERCISE|27 Videos

Similar Questions

Explore conceptually related problems

Calculate DeltaG^@ of reaction 2Fe^(3+)+2I^-to2Fe^(2+)+I_2 Given: E_(Fe^(3+)//Fe^(2+))^@ = 0.77V , E_(I_2//I^-)^@ = 0.53V

Find the E_(cell)^(@) for the following cel reaction Fe^(+2)+Zn rarr Zn^(+2)+Fe Given E_(Zn//Zn^(+2))^(@)=0.76V,E_(Fe//Fe^(+2))^(@)=+0.41 V

Calculate at 25^(@) C , the equilibrium constant for the reaction : 2 Fe^(3+) + Sn^(2+) hArr 2 Fe^(2+) + Sn^(4+) Given that E_((Fe^(3+)|Fe^(2+)))^(Theta) = 0.771 V , E_((Sn^(4+) |Sn^(2+)))^(Theta) = 0.150 V

Show that E_(Fe^(+3)//Fe^(+2))^(@) =3E_(Fe^(+3)//Fe)^(@)-2E_(Fe^(+2)//Fe)^(@)

KVPY PREVIOUS YEAR-MOCK TEST 3-EXERCISE
  1. Which of the following arrangements does not represent the correct ord...

    Text Solution

    |

  2. An excess of liquid mercury is added to an acidicfied solution of 1.0x...

    Text Solution

    |

  3. In the following monobromination reaction, the number of possible chir...

    Text Solution

    |

  4. Which one of the following orders presents the correct sequence of the...

    Text Solution

    |

  5. Vapour pressure of solution containing 6 g of a non-volatile solute in...

    Text Solution

    |

  6. The density of gold is 19g//cm^3. If 1.9xx10^-4g of gold is dispersed ...

    Text Solution

    |

  7. At 27^(@)C, hydrogen is leaked through a tiny hole into a vessel for 2...

    Text Solution

    |

  8. Calculate DeltaG^(@) for the reaction : Cu^(2+)(aq) +Fe(s) hArr Fe^(2+...

    Text Solution

    |

  9. If enthalpies of methane and enthane are respectively 320 and 560 calo...

    Text Solution

    |

  10. A sample of 16 g charcoal was brought into contact with CH(4) gas cont...

    Text Solution

    |

  11. In which of the following pairs, there is greatest difference in the o...

    Text Solution

    |

  12. Among the following series of transition metal ions, the one where all...

    Text Solution

    |

  13. The hydroxyl compound that gives a precipitate immediately when treate...

    Text Solution

    |

  14. The radii of Na^+ and Cl^- ions are 95 pm and 181 pm respectively. The...

    Text Solution

    |

  15. A metal oxide has the formula Z(2)O(3) . It can be reduced by hydrogen...

    Text Solution

    |

  16. Consider the following reactions in which all the reactants and the pr...

    Text Solution

    |

  17. Two beaker A and B present in a closed vessel. Beaker A contains 152.4...

    Text Solution

    |

  18. A certain buffer solution contains equal concentration of X^- and HX. ...

    Text Solution

    |

  19. Among the following compounds, the one that gets hydrolysed to form me...

    Text Solution

    |

  20. Which of the following pair of complexes have the same EAN of the cent...

    Text Solution

    |