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Two metals X and Y form covalent halides...

Two metals X and Y form covalent halides.Both halides can act as Lewis acids and a catalyst in Friedel Crafts reaction. Halide of X is polymer in the solid state and a dimer in the vapour state which decomposes to monomer at 1200 K. However, halide of Y is a dimer in vapour state and becomes ionic in polar solvent. X and Y are respectively

A

Be,AI

B

Al,Be

C

Be,Ca

D

Mg,Ca

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Carbon-oxygent bond in ethers can be cleaved b halogen acids, sulphuric acid, phosphorus pentachlodie, etc. The cleavage of C-O bond take place under drastic conditions with excess of hydrogen halides. R-O-R+2HX rarr 2RX +H_(2)O If hydrogen halide is not taken in excess then a molecule of alcohol and alkyl halide are formed. R-O-R+HI overset(373K) (rarr) R-OH+R-I The order of reactivity of hydrogen halides towards the given reaction depends on the bond strength of halogenated acids, weaker is the H-X bond, greter is its reactivity. In case of unsymmetrical ethers, the site of cleavage is such that the halide is formed from the alkyl group which is smaller in size. However, when one of the alkyl group is tertiary, the halide formed is the tertiary halide. Indiate wheterh the following statements // reactions are true or false. The order of hydrogen halide reactivity is, HI lt HBr lt HCl . (a) True (b) False

Carbon-oxygent bond in ethers can be cleaved b halogen acids, sulphuric acid, phosphorus pentachlodie, etc. The cleavage of C-O bond take place under drastic conditions with excess of hydrogen halides. R-O-R+2HX rarr 2RX +H_(2)O If hydrogen halide is not taken in excess then a molecule of alcohol and alkyl halide are formed. R-O-R+HI overset(373K) (rarr) R-OH+R-I The order of reactivity of hydrogen halides towards the given reaction depends on the bond strength of halogenated acids, weaker is the H-X bond, greter is its reactivity. In case of unsymmetrical ethers, the site of cleavage is such that the halide is formed from the alkyl group which is smaller in size. However, when one of the alkyl group is tertiary, the halide formed is the tertiary halide. Indiate wheterh the following statements // reactions are true or false. Alkyl aryl ethers react with HI to give phenol and alkyl halide. (a) True (b) False

Carbon-oxygent bond in ethers can be cleaved b halogen acids, sulphuric acid, phosphorus pentachlodie, etc. The cleavage of C-O bond take place under drastic conditions with excess of hydrogen halides. R-O-R+2HX rarr 2RX +H_(2)O If hydrogen halide is not taken in excess then a molecule of alcohol and alkyl halide are formed. R-O-R+HI overset(373K) (rarr) R-OH+R-I The order of reactivity of hydrogen halides towards the given reaction depends on the bond strength of halogenated acids, weaker is the H-X bond, greter is its reactivity. In case of unsymmetrical ethers, the site of cleavage is such that the halide is formed from the alkyl group which is smaller in size. However, when one of the alkyl group is tertiary, the halide formed is the tertiary halide. Indiate wheterh the following statements // reactions are true or false. In the reaction, R-O-R+HX rarr RX+ROH , oxonium [R-underset(H)underset(|)overset(+)(O)-R] ioin is formed as intermediate. (a) True (b) False

KVPY PREVIOUS YEAR-MOCK TEST 6-EXERCISE
  1. In the following reactions,

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  2. Potassium has a bcc structure with nearest neighour distance 4.52 Åits...

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  3. A 0.6gm sample consisting of only CaC(2)O(4) and MgC(2)O(4) is heated ...

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  4. Formation of polyethylene from calcium carbide takes place as follows ...

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  5. Which of the following, when mixed, will give a solution with pHgt7 ?

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  6. Calculate the freezing point of a solution containing 8.1 g of HBr in ...

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  7. Consider the following reactions: MX(4)+X'(2) to MX(4)X(2)' If ato...

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  8. A compound 'X' on ozonolysis followed by reduction gives an aldehyde, ...

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  9. The correct order of magnetic moments (spin values in B.M.) among is:

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  10. The ammonia evolved from the treatment of 0.03 g of an organic compoun...

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  11. In an electrolysis experiment, current was passed for 5h through two c...

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  12. Based on the given diagram, which of the following statements regardin...

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  13. The rate constant for the decomposition of a certain substance is 2.8...

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  14. Which of the following combination will produce H(2) gas ?

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  15. For the following molecules : PCl(5), BrF(3), IC l(2)^(-), XeF(5)^(-...

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  16. Which of the following expression is correct for packing fraction of N...

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  17. Two metals X and Y form covalent halides.Both halides can act as Lewis...

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  18. Among [Ni(CO)(4)], [NiCl(4)]^(2-), [Co (NH(3))(4) Cl(2)] Cl, Na(3) [C...

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  19. A mixture of CuSO(4).5H(2)O" and "MgSO(4). 7H(2)O was heated until all...

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  20. For the reaction Ag(CN)(2)^(ɵ)hArr Ag^(o+)+2CN^(ɵ), the K(c ) at 25^...

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