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Low spin complex of d^6-cation in an oct...

Low spin complex of `d^6`-cation in an octahedral field will have the following energy:

A

`(-12)/5 Delta_0+P`

B

`(-12)/5 Delta_0+3P`

C

`(-2)/5 Delta_0+2P`

D

`(-2)/5 Delta_0+P`

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Which is low spin complex?

In which of the following complex ions, the magnitude of Delta_(@) (CFSE in octahedral field ) will be minimum ?

Knowledge Check

  • High spin complex of d^6 configuration in an octahedral field will have the CFSE equal to

    A
    `(-12)/5 triangle_circ`
    B
    `(-14)/5 triangle_circ`
    C
    `(-41)/5 triangle_circ`
    D
    `(-2)/5 triangle_circ`

  • Low spin complex is formed by :

    A
    `sp^(3)d^(2)` hybridization
    B
    `sp^(3)d` hybridization
    C
    `d^(2)sp^(3)` hybridization
    D
    `sp^(3)` hybridization

  • Low spin complex is formed by :

    A
    `sp^(3)d^(2)` hybridization
    B
    `sp^(3)d` hybridization
    C
    `d^(2)sp^(3)` hybridization
    D
    `sp^(3)` hybridization

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    …………is a low spin complex.

    In an octahedral crystal field, the correct set of low orbitals are

    Which one of the following high-spin complexes has the largest CFSE (Crystal field stabillization energy) ?

    According to crystal field theory d-orbitals split up in octahedral field into two sets. d_(xy)d_(yx)d_(zx) have lower energy and d_(x^(2)-y^(2)) and d_(z^(2)) have higher energy. The difference in energy of these two sets of d-orbitals is called crystal field splitting energy denoted by Delta_(0) . In tetrahedral field d_(x^(2)-y^(2)) and d_(z^(2) have lower energy whereas d_(xy)d_(yz)d_(zx) have higher energy. The difference in energy is denoted Delta_(t) . Delta_(0) can be determined by measuring lambda_(max) for absorption and converting into energy units. Delta_(0) depends upon nature of metal ions as well as nature of ligands. The magnitude of Delta_(0) also decides low energy levels are filled. Which of the following is low spin due to strong field ligands?

    Spin only magnetic moments of a d^(8) ion in octahedral square planar and tetrahedral complexes, respectively are .

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