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Which of the following statements is cor...

Which of the following statements is correct for BrF?

A

Total number of lone pairs present in 15.

B

Total number of maximum number of atoms in one plane = 5.

C

Molecule is polar.

D

Bromine has its maximum covalency, in this molecule.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is correct for the molecule BrF (bromine monofluoride), we can analyze the properties and characteristics of this interhalogen compound step by step. ### Step 1: Identify the Nature of BrF BrF is an interhalogen compound formed by the bonding of two halogens: bromine (Br) and fluorine (F). **Hint:** Interhalogen compounds are formed by the combination of two different halogens. ### Step 2: Determine Electronegativity Fluorine is more electronegative than bromine. This means that in the Br-F bond, fluorine will attract the shared electrons more strongly than bromine, resulting in a dipole moment. **Hint:** Electronegativity differences can create partial charges (δ+ and δ-) in a molecule. ### Step 3: Analyze Valence Electrons Bromine has 7 valence electrons and fluorine also has 7 valence electrons. When they bond, one valence electron from bromine is used to form a bond with fluorine. Therefore, bromine will have 6 remaining electrons, which will exist as 3 lone pairs. **Hint:** Count the total valence electrons and how they are used in bonding and lone pairs. ### Step 4: Count the Total Number of Lone Pairs In BrF, bromine has 3 lone pairs (6 electrons), and fluorine has 3 lone pairs (6 electrons). Therefore, the total number of lone pairs in the molecule is 6 (3 from Br and 3 from F). **Hint:** Remember to count lone pairs from both atoms in the molecule. ### Step 5: Determine Molecular Polarity Due to the difference in electronegativity between bromine and fluorine, BrF is a polar molecule. The dipole moment created by the unequal sharing of electrons results in a partial negative charge on fluorine and a partial positive charge on bromine. **Hint:** A molecule is polar if it has a net dipole moment. ### Step 6: Assess Covalence of Bromine Bromine can exhibit different covalency levels. In BrF, bromine has a covalency of 1. However, bromine can form other compounds (like BrF3) where it exhibits higher covalency. **Hint:** Covalency can vary based on the number of bonds formed by an atom in different compounds. ### Conclusion Based on the analysis: - The statement regarding the total number of lone pairs being 15 is incorrect (it is 6). - The statement about the maximum number of atoms in the plane being 5 is incorrect. - The statement that BrF is polar is correct. - The statement about bromine having maximum covalence in this molecule is incorrect. Thus, the correct statement for BrF is that it is a polar molecule. ### Summary of Correct Statement: BrF is a polar molecule due to the electronegativity difference between bromine and fluorine.
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