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If the oxidation state of central atom i...

If the oxidation state of central atom in `BH_3` is +3, then the oxidation states of the central atom in `SiH_4 and CH_4` are, respectively,

A

+ 4,-4

B

+4, +4

C

-4, +4

D

` -4,-4`

Text Solution

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The correct Answer is:
To determine the oxidation states of the central atoms in SiH₄ and CH₄, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Oxidation States**: The oxidation state of an element in a compound is a measure of the degree of oxidation of that element. In a neutral compound, the sum of the oxidation states must equal zero. 2. **Analyzing CH₄ (Methane)**: - The central atom is Carbon (C). - Hydrogen (H) has an oxidation state of +1. - Let the oxidation state of Carbon be \( x \). - Since there are four Hydrogen atoms, the equation for the oxidation state can be set up as: \[ x + 4(+1) = 0 \] - Simplifying this gives: \[ x + 4 = 0 \implies x = -4 \] - Therefore, the oxidation state of Carbon in CH₄ is **-4**. 3. **Analyzing SiH₄ (Silane)**: - The central atom is Silicon (Si). - Similar to Carbon, Hydrogen (H) has an oxidation state of +1. - Let the oxidation state of Silicon be \( y \). - The equation for the oxidation state can be set up as: \[ y + 4(+1) = 0 \] - Simplifying this gives: \[ y + 4 = 0 \implies y = -4 \] - Therefore, the oxidation state of Silicon in SiH₄ is also **-4**. 4. **Final Answer**: The oxidation states of the central atoms in SiH₄ and CH₄ are both **-4**. ### Summary: - Oxidation state of Carbon in CH₄ = -4 - Oxidation state of Silicon in SiH₄ = -4
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