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If for any raction , th rate constant is...

If for any raction , th rate constant is equal to the rate of the reaction at all concentrations, the order is

A

0

B

2

C

1

D

3

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The correct Answer is:
To solve the question, we need to analyze the relationship between the rate constant (k) and the rate of reaction (R) in terms of the order of the reaction. ### Step-by-Step Solution: 1. **Understand the Rate Law Expression**: The rate of a chemical reaction can be expressed using the rate law: \[ R = k [A]^n \] where \( R \) is the rate of reaction, \( k \) is the rate constant, \([A]\) is the concentration of the reactant, and \( n \) is the order of the reaction. 2. **Setting Up the Condition**: According to the question, it is stated that the rate constant \( k \) is equal to the rate of the reaction \( R \) at all concentrations. This can be expressed as: \[ k = R \] 3. **Substituting the Rate Law**: From the rate law, we can substitute \( R \) with \( k [A]^n \): \[ k = k [A]^n \] 4. **Simplifying the Equation**: We can simplify the equation by dividing both sides by \( k \) (assuming \( k \neq 0 \)): \[ 1 = [A]^n \] 5. **Analyzing the Condition**: The equation \( [A]^n = 1 \) must hold true for all concentrations of \( [A] \). The only way this can be true for any concentration is if \( n = 0 \). This is because any number raised to the power of 0 is equal to 1: \[ [A]^0 = 1 \] 6. **Conclusion**: Therefore, if the rate constant is equal to the rate of the reaction at all concentrations, the order of the reaction must be 0. Thus, the final answer is: **The order of the reaction is 0.**
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RC MUKHERJEE-CHEMICAL KINETICS-OBJECTIVE PROBLEMS
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  2. If the rate constant k of a reaction is 1.6 times 10^–3(mol//l)(min^–...

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  3. If for any raction , th rate constant is equal to the rate of the reac...

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  4. Which of the following procedures will lead to a change in the rate co...

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  5. If a reaction with t(1//2)=69.3 seconds , has a rate constant value o...

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  6. The specfic reaction rate constant for a first order reaction is 1xx10...

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  7. k for a zero order reaction is 2xx10^(-2) mol . L^(-1)s^(-1) . If the ...

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  8. A first order reaction is carried out with an initial concentration of...

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  9. Which of the following curves represents a third order reaction ?

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  10. Which of the following curves represents a zero order reaction ? [(a-x...

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  11. 75 % of a first order reaction was completed in 32 min . When was 50 %...

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  12. If doubting the initial concentrations of a reactant doubles t(1/2) of...

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  13. For a given reaction the logarithm of the concentration of the reactan...

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  14. The concept of t(1/2) is useful for the reactions of

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  15. The half - life for a given reaction was halved as the initial concent...

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  16. The rate constant fro a second order reaction is 8 xx 10^(-5) M^(-1) "...

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  17. The rate for a first -order reaction is 8 xx10^(-5) M^(-1)min^(-1). Ho...

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  18. What fraction of a reactant remains after 40 min if t(1/2) is 20 min a...

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  19. For a given reaction, the half-life period was found to be directly pr...

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  20. From different sets of data of t(1//2) at diifferent initial concentra...

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