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When the concentration of a reactant , A...

When the concentration of a reactant , A in a reaction `A to ` Products , is doubled the rate of the reaction increases seven times , the order of the reaction is between

A

0 & 1

B

1 & 2

C

2 & 3

D

3 & 4

Text Solution

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The correct Answer is:
To determine the order of the reaction when the concentration of reactant A is doubled and the rate of the reaction increases seven times, we can follow these steps: ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate of the reaction can be expressed as: \[ R = k[A]^n \] where \( R \) is the rate of the reaction, \( k \) is the rate constant, \( [A] \) is the concentration of reactant A, and \( n \) is the order of the reaction. 2. **Initial Rate**: Let the initial concentration of A be \( [A] \). Thus, the initial rate \( R_1 \) can be written as: \[ R_1 = k[A]^n \] 3. **Final Rate After Doubling Concentration**: When the concentration of A is doubled, the new concentration becomes \( 2[A] \). The new rate \( R_2 \) can be expressed as: \[ R_2 = k(2[A])^n = k \cdot 2^n \cdot [A]^n \] 4. **Relate the Rates**: According to the problem, when the concentration is doubled, the rate increases seven times: \[ R_2 = 7R_1 \] Substituting the expressions for \( R_1 \) and \( R_2 \): \[ k \cdot 2^n \cdot [A]^n = 7(k[A]^n) \] 5. **Cancel Out Common Terms**: We can cancel \( k[A]^n \) from both sides (assuming \( k \) and \( [A] \) are not zero): \[ 2^n = 7 \] 6. **Solve for \( n \)**: To find \( n \), we take the logarithm: \[ n = \log_2(7) \] Using the change of base formula: \[ n = \frac{\log_{10}(7)}{\log_{10}(2)} \] Calculating the approximate values: - \( \log_{10}(7) \approx 0.845 \) - \( \log_{10}(2) \approx 0.301 \) Thus, \[ n \approx \frac{0.845}{0.301} \approx 2.81 \] 7. **Determine the Range of the Order**: Since \( n \approx 2.81 \), we can conclude that the order of the reaction is between 2 and 3. ### Conclusion: The order of the reaction is between 2 and 3.
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