Home
Class 12
CHEMISTRY
For the chemical reaction of the type ...

For the chemical reaction of the type
`2A to 1/2B `
the correct relationship amongst the rate expressions is

A

`-2(d[A])/(dt)=+I/2(d[B])/(dt)`

B

`+2 (d[A])/(dt) =-1/2 (d[R])/(dt)=+2(d[B])/(dt)`

C

`+2 (d[A])/(dt) =-1/2 (d[R])/(dt)=+2(d[B])/(dt)`

D

`+1/2 (d[A])/(dt)=-2(d[B])/(dt)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem regarding the rate expressions for the chemical reaction \(2A \rightarrow \frac{1}{2}B\), we need to derive the correct relationships among the rate expressions of the reactants and products. ### Step-by-Step Solution: 1. **Write the Reaction**: The given reaction is: \[ 2A \rightarrow \frac{1}{2}B \] 2. **Define Rate of Reaction**: The rate of a reaction is generally defined in terms of the change in concentration of reactants and products over time. For the disappearance of reactants and the formation of products, we can express this as: \[ \text{Rate} = -\frac{d[A]}{dt} = \frac{d[B]}{dt} \] 3. **Incorporate Stoichiometry**: For the reaction \(2A \rightarrow \frac{1}{2}B\), we need to account for the stoichiometry: - The stoichiometric coefficient for \(A\) is 2. - The stoichiometric coefficient for \(B\) is \(\frac{1}{2}\). Therefore, the rate expressions can be written as: \[ -\frac{1}{2} \frac{d[A]}{dt} = \frac{1}{\frac{1}{2}} \frac{d[B]}{dt} \] 4. **Rearranging the Rate Expressions**: From the stoichiometric relationships, we can express the rates as: \[ -\frac{1}{2} \frac{d[A]}{dt} = 2 \frac{d[B]}{dt} \] This indicates that: \[ \frac{d[B]}{dt} = -\frac{1}{4} \frac{d[A]}{dt} \] 5. **Final Rate Expression**: Thus, we can summarize the relationships as: \[ -\frac{1}{2} \frac{d[A]}{dt} = \frac{1}{2} \frac{d[B]}{dt} \] This leads us to conclude that: \[ \frac{d[A]}{dt} = -2 \frac{d[B]}{dt} \] 6. **Identifying the Correct Option**: Based on the derived relationships, we can now match these expressions with the given options in the question. The correct option will show that the rate of disappearance of \(A\) is twice the rate of formation of \(B\), with appropriate signs.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    RC MUKHERJEE|Exercise PROBLEMS |42 Videos
  • CHEMICAL EQUIVALENCE

    RC MUKHERJEE|Exercise PROBLEMS|24 Videos
  • CHEMICAL THERMODYNAMICS

    RC MUKHERJEE|Exercise Objective problems|58 Videos

Similar Questions

Explore conceptually related problems

Conside the chemical reaction, N_(2)(g) + 3H_(2)(g)rarr2NH_(3)(g) The rate of reaction can be expressed in terms of time derrivate of concentration of N_(2)(g), H_(2)(g) or NH_(3) (g) Identift the correct relationship amongst the rate expression :

Conisder the chemical reaction N_(2)(g) + 3H_(2)(g) rarr 2NH_(3)(g) The rate of this reaction can be expressed in terms of time derivatives of the concentration of N_(2)(g), H_(2)(g) , or NH_(3)(g) . Identify the correct relationship among the rate expresisons.

Rate law for a chemical reactions is : Rate =k[A]^(1//2)[B]^(1) Choose the correct options among the following :

For a chemical reaction rate law is, rate = k{A]^(2)[B] . If [A] is doubled at constant [B], the rate of reaction

RC MUKHERJEE-CHEMICAL KINETICS-OBJECTIVE PROBLEMS
  1. When the concentration of a reactant , A in a reaction A to Products ...

    Text Solution

    |

  2. When the concentration of a reactant ,A to products , is doubled In fi...

    Text Solution

    |

  3. For a second -order reaction of the type underset (a-a) overset (a) (...

    Text Solution

    |

  4. 50 % of a zero order reaction completes in 10 minutes .100 % of the s...

    Text Solution

    |

  5. The rate constant ,k, of a second -order reaction ,A to Products is g...

    Text Solution

    |

  6. In which of the reaction of the following orders the molecularity and ...

    Text Solution

    |

  7. Which of the following curves represent(s) a zero-order reaction?

    Text Solution

    |

  8. A plot of reactant concentration versus time for a reaction is a strai...

    Text Solution

    |

  9. Conisder the chemical reaction N(2)(g) + 3H(2)(g) rarr 2NH(3)(g) T...

    Text Solution

    |

  10. If the rate constant for a reaction repreasented by 2HI rarr H(2)+I(2)...

    Text Solution

    |

  11. For the chemical reaction of the type 2A to 1/2B the correct rela...

    Text Solution

    |

  12. For what type of the following reactions is the law of mass action, ne...

    Text Solution

    |

  13. If the rate law of a reaction n(A) to B is expressed as underset("mo...

    Text Solution

    |

  14. The exothermic reaction between substances A and B is presented in the...

    Text Solution

    |

  15. Which curve corresponds to the temperature dependence of the rate R of...

    Text Solution

    |

  16. For the first order reaction 2N(2)O(5)(g) rarr 4NO(2)(g) + O(2)(g)

    Text Solution

    |

  17. The rate of a reaction doubles when its temperature changes form 300 K...

    Text Solution

    |

  18. In the reaction, P+Q rarr R+S the time taken for 75% reaction of P i...

    Text Solution

    |

  19. The initial rate of hydrolysis of methyl acetate (1M) by a weak acid (...

    Text Solution

    |

  20. For the non-stoichiometric reaction 2A +B rarr C+D, The following data...

    Text Solution

    |