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Sodium has body centred packing. Distanc...

Sodium has body centred packing. Distance between two nearest atoms is `3.7 Å`. The lattice parameter is

A

`6.8 Å`

B

`4.3 Å`

C

`3.0 Å`

D

`8.6 Å`

Text Solution

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The correct Answer is:
To find the lattice parameter \( a \) for sodium, which has a body-centered cubic (BCC) structure, we can use the relationship between the nearest neighbor distance \( b \) and the lattice parameter \( a \). ### Step-by-Step Solution: 1. **Understanding the BCC Structure**: In a body-centered cubic (BCC) structure, there are two atoms per unit cell: one at each corner of the cube and one in the center. The nearest neighbor distance \( b \) is the distance between the atom at the center and one of the corner atoms. 2. **Formula for Nearest Neighbor Distance**: The relationship between the nearest neighbor distance \( b \) and the lattice parameter \( a \) for a BCC structure is given by the formula: \[ b = \frac{\sqrt{3}}{2} a \] 3. **Rearranging the Formula**: To find the lattice parameter \( a \), we can rearrange the formula: \[ a = \frac{2b}{\sqrt{3}} \] 4. **Substituting the Given Value**: We are given that the distance between two nearest atoms \( b \) is \( 3.7 \, \text{Å} \). We can substitute this value into the rearranged formula: \[ a = \frac{2 \times 3.7 \, \text{Å}}{\sqrt{3}} \] 5. **Calculating the Value**: Now, we calculate \( a \): \[ a = \frac{7.4 \, \text{Å}}{\sqrt{3}} \approx \frac{7.4 \, \text{Å}}{1.732} \approx 4.27 \, \text{Å} \] 6. **Final Result**: Rounding off, we can say that the lattice parameter \( a \) is approximately \( 4.3 \, \text{Å} \). ### Conclusion: The lattice parameter \( a \) for sodium with a body-centered cubic structure, given the nearest neighbor distance of \( 3.7 \, \text{Å} \), is approximately \( 4.3 \, \text{Å} \).
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