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If the lattice parameter for a crystalli...

If the lattice parameter for a crystalline structure is `3.6Å`, then the atomic radius is fcc crystals is

A

`1.81 Å`

B

`2.10Å`

C

`2.92 Å`

D

`1.27 Å`

Text Solution

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The correct Answer is:
To find the atomic radius of a face-centered cubic (FCC) crystal given the lattice parameter, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the FCC Structure**: In a face-centered cubic (FCC) structure, there are atoms located at each of the corners of the cube and at the center of each face. 2. **Identify the Lattice Parameter**: The lattice parameter (denoted as `a`) is the length of the edge of the cubic unit cell. In this case, the lattice parameter is given as `3.6 Å`. 3. **Relate the Atomic Radius to the Lattice Parameter**: In an FCC structure, the relationship between the atomic radius (denoted as `R`) and the lattice parameter is given by the formula: \[ \sqrt{2}a = 4R \] This equation arises because the diagonal of the face of the cube spans across 4 atomic radii (2 radii from each of the two atoms at the ends of the diagonal). 4. **Rearrange the Formula**: To find the atomic radius `R`, we can rearrange the formula: \[ R = \frac{\sqrt{2}a}{4} \] or equivalently, \[ R = \frac{a}{2\sqrt{2}} \] 5. **Substitute the Lattice Parameter**: Now, substitute the given value of the lattice parameter `a = 3.6 Å` into the formula: \[ R = \frac{3.6 \, \text{Å}}{2\sqrt{2}} \] 6. **Calculate the Atomic Radius**: First, calculate the denominator: \[ 2\sqrt{2} \approx 2 \times 1.414 \approx 2.828 \] Now, divide: \[ R \approx \frac{3.6}{2.828} \approx 1.27 \, \text{Å} \] 7. **Conclusion**: The atomic radius of the FCC crystal is approximately `1.27 Å`. ### Final Answer: The atomic radius of the FCC crystal is `1.27 Å`.
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