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At 10^(@)C, the value of the density of ...

At `10^(@)C`, the value of the density of a fixed mass of an ideal gas divided by its pressure is x. at `110^(@)C`, this ratio is

A

x

B

`(383)/(283) x`

C

`(10)/(110) x`

D

`(283)/(383) x`

Text Solution

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To solve the problem, we need to find the ratio of the density of a fixed mass of an ideal gas divided by its pressure at two different temperatures. We are given that at \(10^\circ C\), this ratio is \(x\), and we need to find this ratio at \(110^\circ C\). ### Step-by-step Solution: 1. **Understand the Ideal Gas Law**: The ideal gas law is given by the equation: \[ PV = nRT \] where \(P\) is the pressure, \(V\) is the volume, \(n\) is the number of moles, \(R\) is the ideal gas constant, and \(T\) is the temperature in Kelvin. 2. **Express Density in Terms of Mass and Volume**: The density \(\rho\) of the gas can be expressed as: \[ \rho = \frac{m}{V} \] where \(m\) is the mass of the gas. 3. **Substitute Density into the Ideal Gas Law**: Rearranging the ideal gas law gives us: \[ V = \frac{nRT}{P} \] Substituting this into the density equation: \[ \rho = \frac{m}{V} = \frac{mP}{nRT} \] 4. **Find the Ratio \(\frac{\rho}{P}\)**: Dividing both sides by \(P\): \[ \frac{\rho}{P} = \frac{m}{nRT} \] This shows that \(\frac{\rho}{P}\) is directly proportional to \(\frac{1}{T}\): \[ \frac{\rho}{P} \propto \frac{1}{T} \] 5. **Calculate the Temperatures in Kelvin**: Convert the temperatures from Celsius to Kelvin: - For \(10^\circ C\): \[ T_1 = 10 + 273 = 283 \, K \] - For \(110^\circ C\): \[ T_2 = 110 + 273 = 383 \, K \] 6. **Set Up the Proportionality**: Using the proportionality established: \[ \frac{\rho_1}{P_1} = x \quad \text{at } T_1 = 283 \, K \] \[ \frac{\rho_2}{P_2} = x' \quad \text{at } T_2 = 383 \, K \] From the proportionality, we have: \[ \frac{x'}{x} = \frac{T_1}{T_2} = \frac{283}{383} \] 7. **Solve for \(x'\)**: Rearranging gives: \[ x' = x \cdot \frac{283}{383} \] 8. **Final Result**: Therefore, the ratio of density to pressure at \(110^\circ C\) is: \[ x' = \frac{283}{383} x \]
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