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One mole of an ideal gas at an initial t...

One mole of an ideal gas at an initial temperature true of `TK` does `6R` joule of work adiabatically. If the ratio of specific heats of this gas at constant pressure and at constant volume is `5//3`, the final temperature of the gas will be

A

`(T + 2.4)K`

B

`(T - 2.4)K`

C

`(T + 4) K`

D

`(T - 4) K`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Understand the Given Information We are given: - Number of moles (n) = 1 mole - Initial temperature (T_i) = T K - Work done (W) = 6R joules - Ratio of specific heats (γ) = 5/3 Since the process is adiabatic, we know that the heat transfer (ΔQ) is zero. ### Step 2: Use the First Law of Thermodynamics The first law of thermodynamics states: \[ \Delta Q = \Delta U + W \] Since ΔQ = 0 for an adiabatic process, we have: \[ 0 = \Delta U + W \] This implies: \[ \Delta U = -W \] Substituting the value of W: \[ \Delta U = -6R \] ### Step 3: Relate Change in Internal Energy to Temperature Change The change in internal energy (ΔU) for an ideal gas can be expressed as: \[ \Delta U = n C_v \Delta T \] Where \(C_v\) is the molar specific heat at constant volume. For a gas with γ = C_p / C_v, we can express \(C_v\) as: \[ C_v = \frac{R}{\gamma - 1} \] Substituting γ = 5/3: \[ C_v = \frac{R}{\frac{5}{3} - 1} = \frac{R}{\frac{2}{3}} = \frac{3R}{2} \] ### Step 4: Substitute ΔU into the Equation Now substituting \(C_v\) into the equation for ΔU: \[ \Delta U = n C_v \Delta T \Rightarrow -6R = 1 \cdot \frac{3R}{2} \Delta T \] This simplifies to: \[ -6R = \frac{3R}{2} \Delta T \] ### Step 5: Solve for ΔT Now, we can solve for ΔT: \[ \Delta T = \frac{-6R \cdot 2}{3R} = -4 \] ### Step 6: Find the Final Temperature The change in temperature (ΔT) is related to the initial and final temperatures: \[ \Delta T = T_f - T_i \] Substituting ΔT = -4: \[ -4 = T_f - T \] Thus, we can rearrange to find the final temperature: \[ T_f = T - 4 \] ### Conclusion The final temperature of the gas is: \[ \boxed{T - 4} \text{ K} \]
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