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E^(@) for the electrochemical cell Zn(...

`E^(@)` for the electrochemical cell
`Zn(s)|Zn^(2+) 1 M (Aq.)||Cu^(2+) 1 M (aq.)|Cu(s)`
is 1.10 V at `25^(@)C`. The equilibrium constant for the cell reaction,
`Zn(s) +Cu^(2+) (aq.) hArr Zn^(2+) (aq.)+Cu(s)`
Will be :

A

(a) `10^(37)`

B

(b) `10^(-28)`

C

(c) `10^(18)`

D

(d) `10^(17)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant (K) for the reaction given the standard cell potential (E°), we can use the relationship between the cell potential and the equilibrium constant. Here are the steps to solve the problem: ### Step-by-Step Solution: 1. **Identify the Reaction and Given Data**: The reaction is: \[ \text{Zn(s)} + \text{Cu}^{2+}(aq) \rightleftharpoons \text{Zn}^{2+}(aq) + \text{Cu(s)} \] The standard cell potential (E°) is given as 1.10 V at 25°C. 2. **Determine the Number of Electrons Transferred (n)**: In this reaction, zinc (Zn) is oxidized to Zn²⁺, losing 2 electrons, while Cu²⁺ is reduced to Cu, gaining 2 electrons. Therefore, the number of electrons transferred (n) is: \[ n = 2 \] 3. **Use the Nernst Equation**: The relationship between the standard cell potential (E°) and the equilibrium constant (K) is given by the equation: \[ E° = \frac{0.0591}{n} \log K \] Rearranging this equation to solve for K gives: \[ \log K = \frac{n \cdot E°}{0.0591} \] 4. **Substitute the Values**: Substitute E° and n into the equation: \[ \log K = \frac{2 \cdot 1.10}{0.0591} \] 5. **Calculate the Value**: Performing the calculation: \[ \log K = \frac{2.20}{0.0591} \approx 37.225 \] 6. **Find K by Taking the Antilog**: To find K, we take the antilog: \[ K = 10^{37.225} \approx 1.67 \times 10^{37} \] Since 1.67 is negligible compared to 10, we can approximate: \[ K \approx 10^{37} \] 7. **Conclusion**: The equilibrium constant for the reaction is: \[ K \approx 10^{37} \] Therefore, the correct answer is option A: \(10^{37}\).

To find the equilibrium constant (K) for the reaction given the standard cell potential (E°), we can use the relationship between the cell potential and the equilibrium constant. Here are the steps to solve the problem: ### Step-by-Step Solution: 1. **Identify the Reaction and Given Data**: The reaction is: \[ \text{Zn(s)} + \text{Cu}^{2+}(aq) \rightleftharpoons \text{Zn}^{2+}(aq) + \text{Cu(s)} ...
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