To determine which ion has 18 electrons in the outermost shell, we need to analyze the electronic configurations of the given ions: Cu⁺, Th⁴⁺, Cs⁺, and K⁺.
### Step-by-Step Solution:
1. **Identify the Atomic Numbers**:
- Copper (Cu) has an atomic number of 29.
- Thorium (Th) has an atomic number of 90.
- Cesium (Cs) has an atomic number of 55.
- Potassium (K) has an atomic number of 19.
2. **Write the Electronic Configurations**:
- **Copper (Cu)**:
- The electronic configuration is:
- 2 electrons in the 1st shell,
- 8 electrons in the 2nd shell,
- 18 electrons in the 3rd shell,
- 1 electron in the 4th shell.
- Configuration: 2, 8, 18, 1.
- **Thorium (Th)**:
- The electronic configuration is:
- 2 electrons in the 1st shell,
- 8 electrons in the 2nd shell,
- 18 electrons in the 3rd shell,
- 32 electrons in the 4th shell,
- 18 electrons in the 5th shell,
- 10 electrons in the 6th shell,
- 2 electrons in the 7th shell.
- Configuration: 2, 8, 18, 32, 18, 10, 2.
- **Cesium (Cs)**:
- The electronic configuration is:
- 2 electrons in the 1st shell,
- 8 electrons in the 2nd shell,
- 18 electrons in the 3rd shell,
- 18 electrons in the 4th shell,
- 8 electrons in the 5th shell,
- 1 electron in the 6th shell.
- Configuration: 2, 8, 18, 18, 8, 1.
- **Potassium (K)**:
- The electronic configuration is:
- 2 electrons in the 1st shell,
- 8 electrons in the 2nd shell,
- 8 electrons in the 3rd shell,
- 1 electron in the 4th shell.
- Configuration: 2, 8, 8, 1.
3. **Determine the Configuration After Ionization**:
- **Cu⁺**: Loses 1 electron from the outermost shell (4th shell).
- New configuration: 2, 8, 18 (18 electrons in the outermost shell).
- **Th⁴⁺**: Loses 4 electrons (2 from the 7th shell and 2 from the 6th shell).
- New configuration: 2, 8, 18, 32, 18, 8 (still has 18 in the 5th shell).
- **Cs⁺**: Loses 1 electron from the outermost shell (6th shell).
- New configuration: 2, 8, 18, 18, 8 (still has 8 in the outermost shell).
- **K⁺**: Loses 1 electron from the outermost shell (4th shell).
- New configuration: 2, 8, 8 (8 electrons in the outermost shell).
4. **Conclusion**:
- The only ion that has 18 electrons in the outermost shell after ionization is **Cu⁺**.
### Final Answer:
The ion with 18 electrons in the outermost shell is **Cu⁺** (option A).