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An organic compound contains carbon, hyd...

An organic compound contains carbon, hydrogen and oxygen. Its elemental analysis gave`C,38.71%` and `H,9.67%`. The empirical formula of the compound would be `:`

A

`CH_(3)O`

B

`CH_(2)O`

C

`CHO`

D

`CH_(4)O`

Text Solution

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The correct Answer is:
To determine the empirical formula of the organic compound containing carbon, hydrogen, and oxygen based on the given percentages, we will follow these steps: ### Step 1: Determine the percentage of oxygen Given: - Percentage of carbon (C) = 38.71% - Percentage of hydrogen (H) = 9.67% To find the percentage of oxygen (O), we subtract the sum of the percentages of carbon and hydrogen from 100%: \[ \text{Percentage of oxygen} = 100\% - (\text{Percentage of carbon} + \text{Percentage of hydrogen}) \] Calculating: \[ \text{Percentage of oxygen} = 100\% - (38.71\% + 9.67\%) = 100\% - 48.38\% = 51.62\% \] ### Step 2: Convert percentages to grams Assuming we have 100 grams of the compound, the masses of each element will be equal to their percentages: - Mass of carbon = 38.71 g - Mass of hydrogen = 9.67 g - Mass of oxygen = 51.62 g ### Step 3: Convert grams to moles Using the atomic masses: - Atomic mass of carbon (C) = 12 g/mol - Atomic mass of hydrogen (H) = 1 g/mol - Atomic mass of oxygen (O) = 16 g/mol Now we convert the masses to moles: \[ \text{Moles of carbon} = \frac{38.71 \text{ g}}{12 \text{ g/mol}} \approx 3.2258 \text{ mol} \] \[ \text{Moles of hydrogen} = \frac{9.67 \text{ g}}{1 \text{ g/mol}} = 9.67 \text{ mol} \] \[ \text{Moles of oxygen} = \frac{51.62 \text{ g}}{16 \text{ g/mol}} \approx 3.2263 \text{ mol} \] ### Step 4: Determine the mole ratio Now we find the mole ratio by dividing each mole value by the smallest number of moles calculated: - Smallest number of moles = 3.2258 (for C and O) \[ \text{Ratio of carbon} = \frac{3.2258}{3.2258} = 1 \] \[ \text{Ratio of hydrogen} = \frac{9.67}{3.2258} \approx 3 \] \[ \text{Ratio of oxygen} = \frac{3.2263}{3.2258} \approx 1 \] ### Step 5: Write the empirical formula From the ratios, we can conclude: - Carbon (C) = 1 - Hydrogen (H) = 3 - Oxygen (O) = 1 Thus, the empirical formula of the compound is: \[ \text{Empirical formula} = \text{C}_1\text{H}_3\text{O}_1 \text{ or simply } \text{C}_1\text{H}_3\text{O} \] ### Final Answer: The empirical formula of the compound is **C₁H₃O**. ---

To determine the empirical formula of the organic compound containing carbon, hydrogen, and oxygen based on the given percentages, we will follow these steps: ### Step 1: Determine the percentage of oxygen Given: - Percentage of carbon (C) = 38.71% - Percentage of hydrogen (H) = 9.67% To find the percentage of oxygen (O), we subtract the sum of the percentages of carbon and hydrogen from 100%: ...
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