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Reduction by LiAlH4 of hydrolysed produc...

Reduction by `LiAlH_4` of hydrolysed product of an ester gives

A

(a) two acids

B

(b) two aldehydes

C

(c) one molecule of alcohol and another of carboxylic acid

D

(d) two alcohols

Text Solution

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The correct Answer is:
To solve the question regarding the reduction by lithium aluminium hydride (LiAlH₄) of the hydrolyzed product of an ester, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Ester**: Let's consider a general ester represented as R-COOR'. Here, R and R' can be any alkyl groups. **Hint**: Remember that an ester consists of a carbonyl group (C=O) adjacent to an ether group (C-O-R). 2. **Hydrolysis of the Ester**: When the ester undergoes hydrolysis (reaction with water), it breaks down into a carboxylic acid and an alcohol. The reaction can be represented as: \[ R-COOR' + H_2O \rightarrow R-COOH + R'-OH \] Here, R-COOH is the carboxylic acid, and R'-OH is the alcohol. **Hint**: Hydrolysis of esters typically yields a carboxylic acid and an alcohol. 3. **Reduction of Hydrolyzed Products**: Now, we take the hydrolyzed products, which are R-COOH (carboxylic acid) and R'-OH (alcohol), and reduce them using LiAlH₄. **Hint**: LiAlH₄ is a strong reducing agent that can reduce carboxylic acids to alcohols. 4. **Reduction Reaction**: The carboxylic acid (R-COOH) will be reduced to an alcohol (R-CH₂OH) when treated with LiAlH₄. The alcohol (R'-OH) remains unchanged. Thus, the products of the reduction will be: \[ R-CH_2OH \quad \text{(from carboxylic acid)} \quad \text{and} \quad R'-OH \quad \text{(unchanged alcohol)} \] **Hint**: The reduction of a carboxylic acid results in the formation of a primary alcohol. 5. **Final Products**: Therefore, after the reduction, we have two alcohols: R-CH₂OH (from the reduction of the carboxylic acid) and R'-OH (the original alcohol). **Hint**: The final products depend on the structure of the original ester and can be the same or different alcohols. ### Conclusion: The final answer is that the reduction of the hydrolyzed product of an ester by LiAlH₄ gives two alcohols. Thus, the correct option is **D: 2 alcohols**.

To solve the question regarding the reduction by lithium aluminium hydride (LiAlH₄) of the hydrolyzed product of an ester, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Ester**: Let's consider a general ester represented as R-COOR'. Here, R and R' can be any alkyl groups. **Hint**: Remember that an ester consists of a carbonyl group (C=O) adjacent to an ether group (C-O-R). ...
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