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The compound formed when malonic ester i...

The compound formed when malonic ester is heated with urea is

A

(a) cinnamic acid

B

(b) butyric acid

C

(c) barbituric acid

D

(d) crotonic acid

Text Solution

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The correct Answer is:
To solve the question regarding the compound formed when malonic ester is heated with urea, we can follow these steps: ### Step 1: Identify the Reactants - **Malonic Ester**: The structure of malonic ester can be represented as: \[ \text{CH}_2(\text{C(=O)OEt})_2 \] where \( \text{OEt} \) represents the ethoxy group (C2H5O). - **Urea**: The structure of urea is: \[ \text{NH}_2\text{C(=O)NH}_2 \] ### Step 2: Understand the Reaction When malonic ester is heated with urea, a condensation reaction occurs. This reaction typically involves the removal of small molecules, such as ethanol (C2H5OH), leading to the formation of a more complex structure. ### Step 3: Write the Reaction During the reaction, two molecules of ethanol are eliminated. The general reaction can be summarized as follows: \[ \text{Malonic Ester} + \text{Urea} \rightarrow \text{Intermediate} + 2 \text{C}_2\text{H}_5\text{OH} \] ### Step 4: Identify the Product The product formed from this reaction is known as **Barbituric Acid**. Its structure can be represented as: \[ \text{C}_4\text{H}_4\text{N}_2\text{O}_3 \] which can also be depicted as: \[ \text{NH}_2\text{C(=O)C(=O)N}\text{H} \] ### Step 5: Conclusion From the options provided: - A) Cinnamic acid - B) Butyric acid - C) Barbituric acid - D) Crotonic acid The correct answer is **C) Barbituric acid**.

To solve the question regarding the compound formed when malonic ester is heated with urea, we can follow these steps: ### Step 1: Identify the Reactants - **Malonic Ester**: The structure of malonic ester can be represented as: \[ \text{CH}_2(\text{C(=O)OEt})_2 \] where \( \text{OEt} \) represents the ethoxy group (C2H5O). ...
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