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The value of equilibrium constant of the...

The value of equilibrium constant of the reaction. `HI(g)hArr(1)/(2)H_2(g)+(1)/(2)I_2(g)` is `8.0` The equilibrium constant of the reaction. `H_2(g)+I_2(g)hArr2HI(g)` will be

A

(a) `(1)/(16)`

B

(b) `(1)/(64)`

C

(c) `16`

D

(d) `(1)/(8)`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the equilibrium constant \( K_2 \) for the reaction: \[ H_2(g) + I_2(g) \rightleftharpoons 2HI(g) \] given that the equilibrium constant \( K_1 \) for the reaction: \[ HI(g) \rightleftharpoons \frac{1}{2} H_2(g) + \frac{1}{2} I_2(g) \] is \( 8.0 \). ### Step-by-Step Solution: 1. **Identify the Given Equilibrium Constant**: - The equilibrium constant \( K_1 \) for the reaction \( HI(g) \rightleftharpoons \frac{1}{2} H_2(g) + \frac{1}{2} I_2(g) \) is given as \( K_1 = 8.0 \). 2. **Write the Expression for \( K_1 \)**: - The expression for the equilibrium constant \( K_1 \) can be written as: \[ K_1 = \frac{[H_2]^{1/2} [I_2]^{1/2}}{[HI]} \] 3. **Determine the Relationship Between \( K_1 \) and \( K_2 \)**: - The second reaction is the reverse of the first reaction multiplied by 2: \[ H_2(g) + I_2(g) \rightleftharpoons 2HI(g) \] - The equilibrium constant for this reaction, \( K_2 \), can be related to \( K_1 \) using the following relationships: - When a reaction is reversed, the equilibrium constant is the reciprocal: \[ K' = \frac{1}{K_1} \] - When the coefficients of a balanced equation are multiplied by a factor, the equilibrium constant is raised to the power of that factor: \[ K_2 = (K')^2 \] 4. **Calculate \( K_2 \)**: - First, find \( K' \): \[ K' = \frac{1}{K_1} = \frac{1}{8.0} = 0.125 \] - Now, square \( K' \) to find \( K_2 \): \[ K_2 = (K')^2 = (0.125)^2 = \frac{1}{64} \] 5. **Final Answer**: - Therefore, the equilibrium constant \( K_2 \) for the reaction \( H_2(g) + I_2(g) \rightleftharpoons 2HI(g) \) is: \[ K_2 = \frac{1}{64} \] ### Conclusion: The value of the equilibrium constant \( K_2 \) is \( \frac{1}{64} \).

To solve the problem, we need to find the equilibrium constant \( K_2 \) for the reaction: \[ H_2(g) + I_2(g) \rightleftharpoons 2HI(g) \] given that the equilibrium constant \( K_1 \) for the reaction: \[ HI(g) \rightleftharpoons \frac{1}{2} H_2(g) + \frac{1}{2} I_2(g) \] ...
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