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The values of DeltaH and DeltaS for the ...

The values of `DeltaH` and `DeltaS` for the reaction,
`C_("graphite")+CO_(2)(g)rarr2CO(g)`
are `170KJ` and `170JK^(-1)` respectively. This reaction will be spontaneous at

A

710 K

B

910 K

C

1110 K

D

510 K

Text Solution

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The correct Answer is:
To determine the temperature at which the reaction \( C_{\text{(graphite)}} + CO_2(g) \rightarrow 2CO(g) \) becomes spontaneous, we can use the Gibbs free energy equation: \[ \Delta G = \Delta H - T \Delta S \] For a reaction to be spontaneous, \(\Delta G\) must be negative. Therefore, we need to find the temperature \(T\) at which: \[ \Delta H - T \Delta S < 0 \] This can be rearranged to: \[ T \Delta S > \Delta H \] ### Step 1: Convert \(\Delta H\) to Joules Given: - \(\Delta H = 170 \, \text{kJ} = 170 \times 10^3 \, \text{J}\) - \(\Delta S = 170 \, \text{J/K}\) ### Step 2: Set up the inequality We need to find \(T\) such that: \[ T \cdot 170 \, \text{J/K} > 170 \times 10^3 \, \text{J} \] ### Step 3: Solve for \(T\) Rearranging the inequality gives: \[ T > \frac{170 \times 10^3 \, \text{J}}{170 \, \text{J/K}} \] ### Step 4: Simplify the expression The \(170\) in the numerator and denominator cancels out: \[ T > 1000 \, \text{K} \] ### Conclusion The reaction will be spontaneous at temperatures greater than \(1000 \, \text{K}\).

To determine the temperature at which the reaction \( C_{\text{(graphite)}} + CO_2(g) \rightarrow 2CO(g) \) becomes spontaneous, we can use the Gibbs free energy equation: \[ \Delta G = \Delta H - T \Delta S \] For a reaction to be spontaneous, \(\Delta G\) must be negative. Therefore, we need to find the temperature \(T\) at which: ...
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