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In acidic medium, H(2)O(2) changes Cr(2)...

In acidic medium, `H_(2)O_(2)` changes `Cr_(2)O_(7)^(2-)` to `CrO_(5)` which has two `(-O-O-)` bonds. Oxidation state of Cr in `CrO_(5)` is

A

`+5`

B

`+3`

C

`+6`

D

`-10`

Text Solution

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The correct Answer is:
To determine the oxidation state of chromium in CrO5, we can follow these steps: ### Step 1: Write the formula for CrO5 We start with the compound CrO5. ### Step 2: Identify the oxidation state of oxygen In most compounds, the oxidation state of oxygen is -2. However, in CrO5, there are two types of oxygen atoms: those that are part of the peroxide (O-O) bonds and those that are in the oxide form. ### Step 3: Count the number of oxygen atoms In CrO5, there are five oxygen atoms in total. Out of these, two are involved in the O-O bonds (peroxide) and three are in the oxide form. ### Step 4: Assign oxidation states to the oxygen atoms - The two oxygen atoms in the O-O bonds have an oxidation state of -1 each. - The three oxygen atoms in the oxide form have an oxidation state of -2 each. ### Step 5: Set up the equation for the oxidation state of chromium Let the oxidation state of chromium be \( X \). The total charge of the compound is neutral (0), so we can write the equation: \[ X + (3 \times -2) + (2 \times -1) = 0 \] ### Step 6: Simplify the equation Substituting the values into the equation gives: \[ X - 6 - 2 = 0 \] This simplifies to: \[ X - 8 = 0 \] ### Step 7: Solve for X Now, solving for \( X \): \[ X = +8 \] ### Step 8: Correct the oxidation state However, we need to account for the fact that the oxygen atoms in the peroxide bonds have a different oxidation state. The correct equation should be: \[ X - 6 = 0 \] So, solving this gives: \[ X = +6 \] ### Conclusion The oxidation state of chromium in CrO5 is +6.

To determine the oxidation state of chromium in CrO5, we can follow these steps: ### Step 1: Write the formula for CrO5 We start with the compound CrO5. ### Step 2: Identify the oxidation state of oxygen In most compounds, the oxidation state of oxygen is -2. However, in CrO5, there are two types of oxygen atoms: those that are part of the peroxide (O-O) bonds and those that are in the oxide form. ...
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