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Jahn - Teller effect is not observed in ...

Jahn - Teller effect is not observed in high spin complexes of
a.`d^(7)`
b.`d^(8)`
c.`d^(4)`
d.`d^(9)`

A

`d^(7)`

B

`d^(8)`

C

`d^(4)`

D

`d^(9)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the Jahn-Teller effect and its relation to high spin complexes, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Jahn-Teller Effect**: - The Jahn-Teller effect describes the geometric distortion of molecules or ions that occurs when they have degenerate electronic states. This distortion lowers the overall energy of the system. 2. **Identify High Spin Complexes**: - High spin complexes are those where the electrons are arranged to maximize the number of unpaired electrons. This typically occurs in transition metal complexes with weak field ligands. 3. **Determine Electronic Configurations**: - For transition metals, the electronic configurations can be represented in terms of d-electrons. The configurations of interest here are: - d⁷ - d⁸ - d⁴ - d⁹ 4. **Analyze Each Configuration**: - **d⁷**: High spin d⁷ complexes can exhibit Jahn-Teller distortion (e.g., in Co²⁺). - **d⁸**: High spin d⁸ complexes do not exhibit Jahn-Teller distortion (e.g., Ni²⁺). - **d⁴**: High spin d⁴ complexes can exhibit Jahn-Teller distortion (e.g., Cr³⁺). - **d⁹**: High spin d⁹ complexes can also exhibit Jahn-Teller distortion (e.g., Cu²⁺). 5. **Conclusion**: - Based on the analysis, the Jahn-Teller effect is not observed in high spin complexes of **d⁸**. Therefore, the correct answer is option **b**. ### Final Answer: **b. d⁸**

To solve the question regarding the Jahn-Teller effect and its relation to high spin complexes, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Jahn-Teller Effect**: - The Jahn-Teller effect describes the geometric distortion of molecules or ions that occurs when they have degenerate electronic states. This distortion lowers the overall energy of the system. 2. **Identify High Spin Complexes**: ...
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