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The total number possible isomers for th...

The total number possible isomers for the complex compound `[Cu^(II)(NH_(3))_(4) [Pt^(II)CI_(4)]` are

A

5

B

6

C

3

D

4

Text Solution

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The correct Answer is:
To determine the total number of possible isomers for the complex compound \([Cu^{II}(NH_3)_4][Pt^{II}Cl_4]\), we will analyze the coordination isomers that can be formed by the ligands around the central metal ions. ### Step-by-Step Solution: 1. **Identify the Coordination Complexes**: - The complex consists of two parts: \([Cu^{II}(NH_3)_4]\) and \([Pt^{II}Cl_4]\). - Copper (Cu) is coordinated with four ammonia (NH₃) ligands. - Platinum (Pt) is coordinated with four chloride (Cl) ligands. 2. **Understand Coordination Isomers**: - Coordination isomers are formed when the ligands around the metal centers are interchanged. - In this case, we can interchange the ligands between the two metal centers (Cu and Pt). 3. **List Possible Isomers**: - **Isomer 1**: \([Cu^{II}(NH_3)_4][Pt^{II}Cl_4]\) (4 NH₃ with Cu and 4 Cl with Pt) - **Isomer 2**: \([Cu^{II}(NH_3)_3Cl][Pt^{II}(NH_3)Cl_3]\) (3 NH₃ with Cu, 1 Cl with Cu, 3 NH₃ with Pt, and 1 Cl with Pt) - **Isomer 3**: \([Cu^{II}(NH_3)Cl_3][Pt^{II}(NH_3)_3Cl]\) (1 NH₃ with Cu, 3 Cl with Cu, 3 NH₃ with Pt, and 1 Cl with Pt) - **Isomer 4**: \([Cu^{II}Cl_4][Pt^{II}(NH_3)_4]\) (4 Cl with Cu and 4 NH₃ with Pt) 4. **Count the Isomers**: - From the above analysis, we can see that there are a total of 4 distinct coordination isomers possible for the given complex. 5. **Conclusion**: - Therefore, the total number of possible isomers for the complex compound \([Cu^{II}(NH_3)_4][Pt^{II}Cl_4]\) is **4**. ### Final Answer: The total number of possible isomers is **4**.

To determine the total number of possible isomers for the complex compound \([Cu^{II}(NH_3)_4][Pt^{II}Cl_4]\), we will analyze the coordination isomers that can be formed by the ligands around the central metal ions. ### Step-by-Step Solution: 1. **Identify the Coordination Complexes**: - The complex consists of two parts: \([Cu^{II}(NH_3)_4]\) and \([Pt^{II}Cl_4]\). - Copper (Cu) is coordinated with four ammonia (NH₃) ligands. - Platinum (Pt) is coordinated with four chloride (Cl) ligands. ...
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