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Among the following orbital bonds, the a...

Among the following orbital bonds, the angle is minimum between

A

`sp^3` bond

B

`p_x and p_y` -orbitals

C

H-O-H in water

D

sp bonds

Text Solution

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The correct Answer is:
To determine which of the given orbital bonds has the minimum angle between them, we will analyze each case step by step. ### Step 1: Analyze sp³ Hybridization - **Hybridization Type**: sp³ - **Geometry**: Tetrahedral - **Bond Angle**: The bond angle in sp³ hybridization is approximately 109.5 degrees. ### Step 2: Analyze px and py Orbitals - **Orbital Type**: px and py - **Orientation**: The px orbital is aligned along the x-axis, and the py orbital is aligned along the y-axis. - **Bond Angle**: The angle between the px and py orbitals is 90 degrees, as they are perpendicular to each other. ### Step 3: Analyze H₂O Molecule - **Molecule**: Water (H₂O) - **Geometry**: The shape is V-shaped due to the presence of two lone pairs on the oxygen atom. - **Bond Angle**: The ideal tetrahedral angle is 109.5 degrees, but due to lone pair repulsion, the bond angle in H₂O is reduced to approximately 104.5 degrees. ### Step 4: Analyze sp Hybridization - **Hybridization Type**: sp - **Geometry**: Linear - **Bond Angle**: The bond angle in sp hybridization is 180 degrees. ### Conclusion Now that we have analyzed all the cases: - sp³: 109.5 degrees - px and py: 90 degrees - H₂O: 104.5 degrees - sp: 180 degrees The minimum bond angle is found between the px and py orbitals, which is **90 degrees**. ### Final Answer The angle is minimum between **px and py orbitals** (Option B).

To determine which of the given orbital bonds has the minimum angle between them, we will analyze each case step by step. ### Step 1: Analyze sp³ Hybridization - **Hybridization Type**: sp³ - **Geometry**: Tetrahedral - **Bond Angle**: The bond angle in sp³ hybridization is approximately 109.5 degrees. ### Step 2: Analyze px and py Orbitals ...
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