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At which one of the following temperatur...

At which one of the following temperature pressure conditions, the deviation of a gas from ideal behavior is expected to be minimum?

A

350 K and 3 atm

B

550 K and 1 atm

C

250 K and 4 atm

D

450 K and 2 atm

Text Solution

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The correct Answer is:
To determine the conditions of temperature and pressure at which the deviation of a gas from ideal behavior is expected to be minimum, we can follow these steps: ### Step 1: Understand Ideal Gas Behavior Ideal gases follow the ideal gas law, which is represented by the equation \( PV = nRT \). In this equation: - \( P \) = pressure - \( V \) = volume - \( n \) = number of moles - \( R \) = universal gas constant - \( T \) = temperature Real gases deviate from this behavior under certain conditions, particularly at high pressures and low temperatures. ### Step 2: Analyze Low Pressure Conditions At very low pressures: - The volume available to the gas molecules is large. - The intermolecular forces (attractive forces) become negligible. - The real gas equation can be simplified to the ideal gas equation since the terms accounting for molecular volume and intermolecular attraction can be ignored. ### Step 3: Analyze High Temperature Conditions At very high temperatures: - The kinetic energy of the gas molecules is high, which means they move rapidly. - The volume occupied by the gas molecules becomes insignificant compared to the total volume of the gas. - The attractive forces between the molecules become negligible, allowing the gas to behave more ideally. ### Step 4: Identify Optimal Conditions From the analysis: - The conditions for a gas to behave ideally are low pressure and high temperature. - Therefore, the optimal conditions for minimum deviation from ideal behavior are low pressure and high temperature. ### Step 5: Conclusion Based on the given options, we need to identify the conditions that represent low pressure and high temperature. If the options include a low pressure (e.g., 1 atm or lower) and a high temperature (e.g., 550 K), then that would be the correct answer. ### Final Answer The correct option will be the one that indicates low pressure and high temperature, which is option B. ---

To determine the conditions of temperature and pressure at which the deviation of a gas from ideal behavior is expected to be minimum, we can follow these steps: ### Step 1: Understand Ideal Gas Behavior Ideal gases follow the ideal gas law, which is represented by the equation \( PV = nRT \). In this equation: - \( P \) = pressure - \( V \) = volume - \( n \) = number of moles - \( R \) = universal gas constant ...
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