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In a closed vessel of 5 litres capacity...

In a closed vessel of 5 litres capacity, 1 g of `O_(2)` is heated from `300` to `600 K`. Which statement is not correct ?

A

Pressure of the gas increases

B

The rate of collision increases

C

The number of moles of gas increases

D

The energy of gaseous molecules increases

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the statements regarding the behavior of oxygen gas (O₂) in a closed vessel when it is heated from 300 K to 600 K. ### Step-by-Step Solution: 1. **Understanding the System**: - We have a closed vessel with a capacity of 5 liters. - The amount of O₂ present is 1 g. - The initial temperature is 300 K and the final temperature is 600 K. 2. **Calculating Moles of O₂**: - To find the number of moles of O₂, we use the formula: \[ \text{Number of moles} (n) = \frac{\text{mass (g)}}{\text{molar mass (g/mol)}} \] - The molar mass of O₂ is approximately 32 g/mol. - Therefore, the number of moles of O₂ is: \[ n = \frac{1 \text{ g}}{32 \text{ g/mol}} = 0.03125 \text{ moles} \] 3. **Applying Gay-Lussac's Law**: - According to Gay-Lussac's law, at constant volume, the pressure of a gas is directly proportional to its absolute temperature: \[ \frac{P_1}{T_1} = \frac{P_2}{T_2} \] - Since the volume is constant (closed vessel), as the temperature increases from 300 K to 600 K, the pressure will also increase. 4. **Analyzing the Statements**: - **Statement A**: "Pressure of the gas increases." - This is correct because as temperature increases, pressure increases at constant volume. - **Statement B**: "The rate of collision increases." - This is also correct because higher temperature means higher kinetic energy, leading to more frequent collisions between gas molecules. - **Statement C**: "The number of moles of gas increases." - This statement is incorrect. The number of moles remains constant in a closed vessel since no gas is added or removed. - **Statement D**: "The energy of gaseous molecules increases." - This is correct because the kinetic energy of gas molecules is proportional to temperature. As temperature increases, the kinetic energy also increases. 5. **Conclusion**: - The statement that is not correct is **Statement C**: "The number of moles of gas increases." ### Summary of the Solution: - The correct answer is that **Statement C** is not correct.

To solve the problem, we need to analyze the statements regarding the behavior of oxygen gas (O₂) in a closed vessel when it is heated from 300 K to 600 K. ### Step-by-Step Solution: 1. **Understanding the System**: - We have a closed vessel with a capacity of 5 liters. - The amount of O₂ present is 1 g. - The initial temperature is 300 K and the final temperature is 600 K. ...
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