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The ionization constant of ammonium hydr...

The ionization constant of ammonium hydroxide is `1.77xx10^(-5)` at `298 K`. Hydrolysis constant of ammonium chloride is

A

`5.65xx10^(-10)`

B

`6.50xx10^(-12)`

C

`5.65xx10^(-13)`

D

`5.65xx10^(-12)`

Text Solution

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The correct Answer is:
To find the hydrolysis constant (K_h) of ammonium chloride (NH4Cl), we can use the relationship between the ionization constant of ammonium hydroxide (K_b) and the hydrolysis constant (K_h) along with the ion product of water (K_w). ### Step-by-Step Solution 1. **Identify the Given Values**: - Ionization constant of ammonium hydroxide (K_b) = \(1.77 \times 10^{-5}\) - Ion product of water (K_w) at 298 K = \(1.0 \times 10^{-14}\) 2. **Write the Relationship Between K_h, K_b, and K_w**: The relationship is given by: \[ K_h = \frac{K_w}{K_b} \] 3. **Substitute the Known Values**: Substitute the values of K_w and K_b into the equation: \[ K_h = \frac{1.0 \times 10^{-14}}{1.77 \times 10^{-5}} \] 4. **Perform the Calculation**: - First, calculate the division: \[ K_h = \frac{1.0 \times 10^{-14}}{1.77 \times 10^{-5}} \approx 5.65 \times 10^{-10} \] 5. **Conclusion**: The hydrolysis constant (K_h) of ammonium chloride is approximately \(5.65 \times 10^{-10}\). ### Final Answer: The hydrolysis constant of ammonium chloride is \(5.65 \times 10^{-10}\).

To find the hydrolysis constant (K_h) of ammonium chloride (NH4Cl), we can use the relationship between the ionization constant of ammonium hydroxide (K_b) and the hydrolysis constant (K_h) along with the ion product of water (K_w). ### Step-by-Step Solution 1. **Identify the Given Values**: - Ionization constant of ammonium hydroxide (K_b) = \(1.77 \times 10^{-5}\) - Ion product of water (K_w) at 298 K = \(1.0 \times 10^{-14}\) ...
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