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The hydride ion H^(-) is a stronger base...

The hydride ion `H^(-)` is a stronger base than its hydroxide ion `OH^(-)`. Which of the following reactions will occurs if sodium hydride (NaH) is dissolved in water ?

A

(a) `2H^(-)(aq)+H_(2)O(l)rarrH_(2)O+H_(2)+2e^(-)`

B

(b) `H^(-)(aq)+H_(2)O(l)rarr OH^(-)+H_(2)`

C

(c) `H^(-)+H_(2)O(l)rarr` No reaction

D

(d) None of the above

Text Solution

Verified by Experts

The correct Answer is:
B

Sodium hydride dissolved in water as
`NaH+H_(2)O rarr NaOH+H_(2)`
or `H^(-)(aq)+H_(2)O(l)rarr OH^(-)+H_(2)uarr`
In the above reaction hydride ion take proton from water molecule and hydrogen gas is evolved.
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Knowledge Check

  • Which of the following reactions give aromatic ion ?

    A
    B
    C
    D
  • Which of the following reactions involve hydride ion transfer?

    A
    `2H-overset(O)overset(||)(C)-Hoverset(overset(ϴ)(O)H)(to)H-overset(O)overset(||)(C)-overset(ϴ)(O)+CH_(3)-OH`
    B
    `2H_(3)C-overset(O)oversett(||)(C)-underset(Delta)overset(overset(ϴ)(O)H)(to)H_(3)C-CH=CH-overset(O)overset(||)(C)-H`
    C
    `2H_(3)C-overset(O)overset(||)(C)-H overset(Al(OEt)_(3))(to)CH_(3)-overset(O)overset(||)(C)-O-CH_(2)CH_(3)`
    D
  • Which of the following compounds will react with sodium hydroxide solution in water ?

    A
    `C_6H_5OH`
    B
    `C_6H_5CH_2OH`
    C
    `(CH_3)_3COH`
    D
    `C_2H_5OH`
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