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The activation energy of a reaction can ...

The activation energy of a reaction can be determined from the slope of which of the following graphs ?

A

in K Vs T

B

`("in" K)/(T) vs T `

C

ln K vs `(1)/(T)`

D

`(T)/("in"K)vs (I)/(T)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the activation energy of a reaction from the slope of a graph, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Relationship**: The activation energy (EA) is related to the rate constant (k) and temperature (T) through the Arrhenius equation: \[ k = A e^{-\frac{E_A}{RT}} \] where A is the pre-exponential factor, R is the universal gas constant, and T is the temperature in Kelvin. 2. **Take the Natural Logarithm**: To linearize the Arrhenius equation, take the natural logarithm of both sides: \[ \ln k = \ln A - \frac{E_A}{R} \cdot \frac{1}{T} \] 3. **Rearrange the Equation**: This can be rearranged into the form of a straight line: \[ \ln k = -\frac{E_A}{R} \cdot \frac{1}{T} + \ln A \] Here, if we let Y = \ln k and X = \frac{1}{T}, we can see that this is in the form of Y = MX + C, where: - M (slope) = -\frac{E_A}{R} - C (y-intercept) = \ln A 4. **Identify the Graph**: The graph that plots \(\ln k\) (Y-axis) against \(\frac{1}{T}\) (X-axis) will yield a straight line. The slope of this line is given by: \[ \text{slope} = -\frac{E_A}{R} \] 5. **Conclusion**: From the slope of the graph of \(\ln k\) vs. \(\frac{1}{T}\), we can determine the activation energy (E_A) of the reaction. ### Final Answer: The activation energy of a reaction can be determined from the slope of the graph of \(\ln k\) versus \(\frac{1}{T}\).

To determine the activation energy of a reaction from the slope of a graph, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Relationship**: The activation energy (EA) is related to the rate constant (k) and temperature (T) through the Arrhenius equation: \[ k = A e^{-\frac{E_A}{RT}} \] ...
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