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Half-life period of a first-order reacti...

Half-life period of a first-order reaction is `1386` seconds. The specific rate constant of the reaction is

A

`5.0xx10^(-3)s^(-1)`

B

`0.5xx10^(-2)S^(-1)`

C

`0.5xx10^(-3)S^(-1)`

D

`5.0xx10^(-3)S^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the specific rate constant (K) of a first-order reaction given the half-life period, we can use the relationship between the half-life (t₁/₂) and the rate constant (K) for first-order reactions. The formula is: \[ t_{1/2} = \frac{0.693}{K} \] ### Step-by-Step Solution: 1. **Identify the given data**: - Half-life period (t₁/₂) = 1386 seconds 2. **Use the formula for half-life of a first-order reaction**: \[ t_{1/2} = \frac{0.693}{K} \] 3. **Rearrange the formula to solve for K**: \[ K = \frac{0.693}{t_{1/2}} \] 4. **Substitute the value of t₁/₂ into the equation**: \[ K = \frac{0.693}{1386} \] 5. **Calculate K**: - Performing the division: \[ K = 0.0005 \text{ (approximately)} \] - This can also be expressed in scientific notation: \[ K = 0.5 \times 10^{-3} \text{ per second} \] 6. **Conclusion**: - The specific rate constant (K) is \( 0.5 \times 10^{-3} \) per second. ### Final Answer: The specific rate constant of the reaction is \( 0.5 \times 10^{-3} \) per second. ---

To find the specific rate constant (K) of a first-order reaction given the half-life period, we can use the relationship between the half-life (t₁/₂) and the rate constant (K) for first-order reactions. The formula is: \[ t_{1/2} = \frac{0.693}{K} \] ### Step-by-Step Solution: 1. **Identify the given data**: - Half-life period (t₁/₂) = 1386 seconds ...
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